Entropy productionEntropy production (or generation) is the amount of entropy which is produced during heat process to evaluate the efficiency of the process. Entropy is produced in irreversible processes. The importance of avoiding irreversible processes (hence reducing the entropy production) was recognized as early as 1824 by Carnot. In 1865 Rudolf Clausius expanded his previous work from 1854 on the concept of "unkompensierte Verwandlungen" (uncompensated transformations), which, in our modern nomenclature, would be called the entropy production.
Detailed balanceThe principle of detailed balance can be used in kinetic systems which are decomposed into elementary processes (collisions, or steps, or elementary reactions). It states that at equilibrium, each elementary process is in equilibrium with its reverse process. The principle of detailed balance was explicitly introduced for collisions by Ludwig Boltzmann. In 1872, he proved his H-theorem using this principle. The arguments in favor of this property are founded upon microscopic reversibility.
Collision theoryCollision theory is a principle of chemistry used to predict the rates of chemical reactions. It states that when suitable particles of the reactant hit each other with the correct orientation, only a certain amount of collisions result in a perceptible or notable change; these successful changes are called successful collisions. The successful collisions must have enough energy, also known as activation energy, at the moment of impact to break the pre-existing bonds and form all new bonds.
Plasma parametersPlasma parameters define various characteristics of a plasma, an electrically conductive collection of charged particles that responds collectively to electromagnetic forces. Plasma typically takes the form of neutral gas-like clouds or charged ion beams, but may also include dust and grains. The behaviour of such particle systems can be studied statistically. All quantities are in Gaussian (cgs) units except energy and temperature which are in electronvolts.
Convection zoneA convection zone, convective zone or convective region of a star is a layer which is unstable due to convection. Energy is primarily or partially transported by convection in such a region. In a radiation zone, energy is transported by radiation and conduction. Stellar convection consists of mass movement of plasma within the star which usually forms a circular convection current with the heated plasma ascending and the cooled plasma descending. The Schwarzschild criterion expresses the conditions under which a region of a star is unstable to convection.
QCD matterQuark matter or QCD matter (quantum chromodynamic) refers to any of a number of hypothetical phases of matter whose degrees of freedom include quarks and gluons, of which the prominent example is quark-gluon plasma. Several series of conferences in 2019, 2020, and 2021 were devoted to this topic. Quarks are liberated into quark matter at extremely high temperatures and/or densities, and some of them are still only theoretical as they require conditions so extreme that they cannot be produced in any laboratory, especially not at equilibrium conditions.
Le Chatelier's principleLe Chatelier's principle (pronounced UKlə_ʃæˈtɛljeɪ or USˈʃɑːtəljeɪ), also called Chatelier's principle (or the Equilibrium Law), is a principle of chemistry used to predict the effect of a change in conditions on chemical equilibria. The principle is named after French chemist Henry Louis Le Chatelier, and sometimes also credited to Karl Ferdinand Braun, who discovered it independently.
Orders of magnitude (temperature)Most ordinary human activity takes place at temperatures of this order of magnitude. Circumstances where water naturally occurs in liquid form are shown in light grey.
Onsager reciprocal relationsIn thermodynamics, the Onsager reciprocal relations express the equality of certain ratios between flows and forces in thermodynamic systems out of equilibrium, but where a notion of local equilibrium exists. "Reciprocal relations" occur between different pairs of forces and flows in a variety of physical systems. For example, consider fluid systems described in terms of temperature, matter density, and pressure.
English Engineering UnitsSome fields of engineering in the United States use a system of measurement of physical quantities known as the English Engineering Units. Despite its name, the system is based on United States customary units of measure. The English Engineering Units is a system of consistent units used in the United States. The set is defined by the following units, and definitive conversions to the International System of Units. Units for other physical quantities are derived from this set as needed.
