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The thermal stability of amorphous ionic solids is usually attributed to kinetic considerations related to mass transport. However, there are a number of amorphous ionic solids, which have recently been described, whose unusual resistance to nucleation and ...
Due to their high hardness, high melting point and high chemical stability, transition metal nitrides present a great interest for various applications. This work constitutes a contribution to the understanding of the properties of Nb based binary and tern ...
Direct reaction between [Cr(CO)6] and arenes with ionic substituents affords the corresponding arene-chromium tricarbonyl complexes, [Cr(CO)3(arene)], in only modest yield. In contrast, these complexes can be prepared in pure form in ...
Two 1,3-dialkyne-functionalized imidazolium chlorides, 1,3-dipropynylimidazolium chloride and 1,3-dipentynylimidazolium chloride, have been prepared from the direct reaction between the appropriate chloroalkyne and (trimethylsilyl)imidazole. Replacement of ...
Four tetracatenar (L1–L4) and one hexacatenar (L5) ligands, derived from the diaza-18-crown-6 framework, are synthesized and characterized. In these ligands, the amine functions are fitted with benzoyloxybenzyl linker groups, attached either with a carbony ...
A process for making hollow composite structures or vessels which includes the steps of: A) heating a mixture of thermoplastic matrix and reinforcing fibres wrapped over a rigid or semi-rigid thermoplastic liner or bladder above the melting point of the th ...
In fluidized-bed gas-phase polymerization reactors, several grades of polyethylene are produced in the same equipment by changing the operating conditions. Transitions between the different grades are rather slow and result in the production of a considera ...
A new laser micro-spot welding procedure for copper has been developed in order to eliminate the shortcomings of existing techniques based on laser pulse shaping or in-situ temperature control. This procedure consists in dividing the welding process in fou ...
A series of imidazolium salts with the nitrile functional group attached to the alkyl side chain, viz. [C(n)CNmim][X] (where C(n)CNmim is the 1-alkylnitrile-3-methylimidazolium cation and C-n = (CH2)(n), n = 1-4; X = Cl, PF6, and BF4) and [C(3)CNdmim][X] ( ...
The invention relates to a process for increasing the melt viscosities of polyester resins. This process comprises a step of heating the polyester resin in the temperature range comprised between the melting temperature of the polyester resin and the degra ...
