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The electrochem. behavior of some model org. compds. on boron-doped synthetic diamond thin film electrodes, obtained by HF-CVD on p-Si substrate was investigated. Only reactions involving simple electron transfer like hydroquinone/benzoquinone are active i ...
The aim of this series of two publications is to characterise radical reactions of organic molecules, occurring in atmospheric water phases. In this second study, the reactions occurring in a mixed peroxyl radical system generated from the OH radical attac ...
Transfer of chirality during the build-up of molecules has been applied innumerable times in organic chemistry since the end of the 19th century, when it was introduced in the so-called asymmetric synthesis by E. Fischer. Although analogous reactions were ...
In aqueous oxidative processes with ozone (O-3), chlorine, or chloramine, naturally occurring iodide (I-) can easily be oxidized to hypoiodous acid (HOI) which can react with natural organic matter (NOM) or he further oxidized to iodate (IO3-). Such proces ...
The anodic oxidn. of 2-naphthol in acid media was studied at a synthetic boron-doped diamond thin film electrode (BDD) using cyclic voltammetry and bulk electrolysis. The results showed that in the potential region, where the supporting electrolyte is stab ...
PCT No. PCT/IB95/00786 Sec. 371 Date Mar. 24, 1998 Sec. 102(e) Date Mar. 24, 1998 PCT Filed Sep. 25, 1995 PCT Pub. No. WO97/12382 PCT Pub. Date Apr. 3, 1997The present invention aims at improving the catalytic activity of the metallic platinum deposited on ...
A new, versatile architecture is presented for microfluidic devices made entirely from glass, for use with reagents which would prove highly corrosive for silicon. Chips consist of three layers of glass wafers bonded together by fusion bonding. On the insi ...
Synthetic B-doped diamond thin film electrodes were tested for electroanal. detection of 2-naphthol. This redox reaction was studied by cyclic voltammetry in aq. acidic soln. Well-resolved oxidn. waves were obsd. and the voltammetric peaks exhibited naphth ...
The present work deals with two subjects. The interaction of NO2 and HONO with different types of soot are examined in the first part whereas in the second part an experimental set-up is presented which has been built in order to measure the kinetics of th ...
The electrochem. oxidns. of some org. compds. have shown that only reactions involving simple electron transfer are active on diamond electrodes in the potential region of water stability. For more complex reactions, diamond electrodes show no electrocatal ...