Concept

Nitrogen

Related publications (401)

Correction: Facile N-functionalization and strong magnetic communication in a diuranium(v) bis-nitride complex (vol 10, pg 3543, 2019)

Marinella Mazzanti, Farzaneh Fadaei Tirani, Ivica Zivkovic, Lucile Sylvie Danielle Chatelain, Luciano Barluzzi

Correction for Facile N-functionalization and strong magnetic communication in a diuranium(v) bis-nitride complex' by Luciano Barluzzi et al., Chem. Sci., 2019, DOI: ; 10.1039/c8sc05721d. ...

2019

Evolution of nitrogen concentration and ammonia production in N-2-seeded H-mode discharges at ASDEX Upgrade

Olivier Sauter, Basil Duval, Stefano Coda, Timothy Goodman, Federico Alberto Alfredo Felici, Cristian Sommariva, Laurie Porte, Antoine Pierre Emmanuel Alexis Merle, Haomin Sun, Richard Pitts, Yann Camenen, Marco Wischmeier, Nicola Vianello, Alberto Bottino, Emiliano Fable, Andrea Scarabosio, Doohyun Kim, Dávid Wágner, Thomas Binderup Jensen, Donghyun Kim, Xiao Wang, Bernhard Sieglin, Otto Asunta, Hartmut Zohm, Emanuele Poli, Gergely Papp, Giovanni Tardini

Ammonia formation was studied in a series of dedicated nitrogen seeded H-mode discharges at ASDEX Upgrade. The evolution of ammonia formation was investigated with a reference phase before the seeding, and a long, stable flat-top nitrogen-seeded phase. It ...

2019

Reactions of aliphatic amines with ozone: Kinetics and mechanisms

Urs von Gunten, Sung Eun Lim

Aliphatic amines are common constituents in micropollutants and dissolved organic matter and present in elevated concentrations in wastewater-impacted source waters. Due to high reactivity, reactions of aliphatic amines with ozone are likely to occur durin ...

PERGAMON-ELSEVIER SCIENCE LTD2019

Tuning the structure, reactivity and magnetic communication of nitride-bridged uranium complexes with the ancillary ligands

Rosario Scopelliti, Marinella Mazzanti, Ivica Zivkovic, Alberto Fabrizio, Luciano Barluzzi

Molecular uranium nitride complexes were prepared to relate their small molecule reactivity to the nature of the U & xe001;N & xe001;U bonding imposed by the supporting ligand. The U4+-U4+ nitride complexes, [NBu4][{(((BuO)-Bu-t)(3)SiO)(3)U}(2)(mu-N)], [NB ...

2019

Ethynylbenziodazolones (EBZ) as Electrophilic Alkynylation Reagents for the Highly Enantioselective Copper-Catalyzed Oxyalkynylation of Diazo Compounds

Rosario Scopelliti, Jérôme Waser, Farzaneh Fadaei Tirani, Durga Prasada Rao Hari, Lionel Schouwey, Verity Barber

Ethynylbenziodoxol(on)e (EBX) cyclic hypervalent iodine reagents are now established reagents for the alkynylation of radicals and nucleophiles, yet they present limited possibilities for further structure and reactivity modification. Herein, the first syn ...

2019

Quantum Dynamics of H-2 and D-2 Confined in Hydrate Structures as a Function of Pressure and Temperature

Philippe Gillet, Richard Gaal, Livia Eleonora Bove Kado, Umbertoluca Ranieri

We present an extensive study of the quantum dynamics of molecular hydrogen trapped within the nanocavities of two hydrate structures at low temperatures, namely, clathrate structure II and filled ice structure Cl. By inelastic neutron scattering measureme ...

AMER CHEMICAL SOC2019

Small Molecule Activation by Multimetallic Uranium Complexes

Marta Falcone

The development of new processes for the selective and sustainable transformation of abundant small molecules constitutes one of the major research areas in inorganic and organometallic chemistry. These molecules as CO2, CO, N2 and H2 are abundant reservoi ...

EPFL2019

Highly stable enzyme-mimicking nanocomposite of antioxidant activity

Bálint Náfrádi, Marko Pavlovic

A highly stable nanocomposite of antioxidant activity was developed by immobilization of a superoxide dismutase-mimicking metal complex on copolymer-functionalized nanoclay. The layered double hydroxide (LDH) nanoclays were synthesized and surface modifica ...

2019

Effect of SiO2 on co-impregnated V2O5/WO3/TiO2 catalysts for the selective catalytic reduction of NO with NH3

Davide Ferri, Oliver Kröcher, Adrian Marberger

Co-impregnation of vanadia and tungsta on titania produced highly active catalysts for the reduction of nitrogen oxides with ammonia but showed aging tendencies at temperatures around 600 degrees C. In order to preserve their low temperature activity after ...

ELSEVIER SCIENCE BV2019

New insights into the effect of nitrogen incorporation in Mo: catalytic hydrogenation vs. hydrogenolysis

Lioubov Kiwi, Fernando Cardenas Lizana, Daniel André Samuel Lamey

The catalytic effect of nitrogen incorporation into Mo on hydrogenation (of -NO2 to -NH2 in nitrobenzene to aniline) and hydrogenolysis (of -C?O in benzaldehyde to toluene) processes has been assessed. Bulk Mo was prepared by temperature programmed reducti ...

ROYAL SOC CHEMISTRY2019

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