Potting and stamping is a modern name for one of the 18th-century processes for refining pig iron without the use of charcoal.
The process was devised by Charles Wood of Lowmill, Egremont in Cumberland and his brother John Wood of Wednesbury and patented by them in 1761 and 1763. The process was improved by John Wright and Joseph Jesson of West Bromwich, who also obtained a patent.
The process involved the melting of pig iron in an oxidising atmosphere. The metal was then allowed to cool, broken up by stamping, and washed. The granulated iron was then heated in pots in a reverberatory furnace. The resultant bloom was then drawn out under a forge hammer in the usual way.
During the 14-year term of the patents, the process was little used except by the inventors. However, from c.1785, shortly before Wright & Jesson's process came out of patent, it seems to have been adopted by many ironmasters in the West Midlands. Professor Charles Hyde argues that the potting and stamping process was largely responsible for a 70% rise in wrought iron production from 1750 to 1788.
Ultimately, the process was replaced by puddling, though it remains unclear how quickly.
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Puddling is the process of converting pig iron to bar (wrought) iron in a coal fired reverberatory furnace. It was developed in England during the 1780s. The molten pig iron was stirred in a reverberatory furnace, in an oxidizing environment to burn the carbon, resulting in wrought iron. It was one of the most important processes for making the first appreciable volumes of valuable and useful bar iron (malleable wrought iron) without the use of charcoal. Eventually, the furnace would be used to make small quantities of specialty steels.
Ferrous metallurgy is the metallurgy of iron and its alloys. The earliest surviving prehistoric iron artifacts, from the 4th millennium BC in Egypt, were made from meteoritic iron-nickel. It is not known when or where the smelting of iron from ores began, but by the end of the 2nd millennium BC iron was being produced from iron ores in the region from Greece to India, and sub-Saharan Africa. The use of wrought iron (worked iron) was known by the 1st millennium BC, and its spread defined the Iron Age.
Wrought iron is an iron alloy with a very low carbon content (less than 0.05%) in contrast to that of cast iron (2.1% to 4%). It is a semi-fused mass of iron with fibrous slag inclusions (up to 2% by weight), which give it a wood-like "grain" that is visible when it is etched, rusted, or bent to failure. Wrought iron is tough, malleable, ductile, corrosion resistant, and easily forge welded, but is more difficult to weld electrically.