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H-1 NMR has been used to characterise white Portland cement paste incorporating 10 wt.% of silica fume. Samples were measured sealed throughout the hydration without sample drying. Paste compositions and C-S-H characteristics are calculated based on H-1 NM ...
A novel fluorescence lifetime imaging microscopy (FLIM) working with deep UV 240-280 nm wavelength excitations has been developed. UV-FLIM is used for measurement of defect-related fluorescence and its changes upon annealing from femtosecond laser-induced ...
Grafting reactive molecular complexes on dehydroxylated amorphous silica is a strategy to develop ``single-site'' heterogeneous catalysts. In general, only the reactivity of isolated silanols is invoked for silica dehydroxylated at 700 degrees C ([SiO2-700 ...
2014
Pyrethroids and organophosphates are among the most toxic insecticides for aquatic organisms, leading to annual-average environmental quality standards (AA-EQS) in the picogram per liter range in surface waters. For monitoring purposes, it is therefore cru ...
Elsevier2014
Proteomics has been one of the main projects challenging biological and analytical chemists for many years. The separation, identification and quantification of all the proteins expressed within biological systems remain the main objectives of proteomics. ...
EPFL2014
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The nanoscale morphology of, and pore water interactions in, calcium silicate hydrate (C-S-H), the active component of cement, remain uncertain. H-1 nuclear magnetic resonance (NMR) can fully characterize the nanoporosity of C-S-H in as-prepared material w ...
Amer Chemical Soc2013
Many efforts have been undertaken in past decades to minimize pollution from municipal solid waste incineration fly ash (MSWI FA). This residue is toxic, because of its high concentration of heavy metals, mainly Pb and Zn. A new method for heavy metals ent ...
RSC Publishing2013
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A plasmonic slot waveguide excited by evanescent wave coupling of a silicon strip waveguide is studied to be used as a label-free biosensor. The plasmonic slot waveguide enables strong electric-field enhancement in a small volume inducing higher interactio ...
Gel electrophoresis has been used for decades as a high-resolution separation technique for proteins and protein isomers, but limited in the coupling with MS because of low throughput and poor automaticity compared with LC-MS. In this work, we have develop ...
One of the most serious causes of degradation of concrete is the alkalisilica reaction. Amorphous silicates present in certain aggregates react with the alkaline pore solution of the concrete to form a gel, which absorbs water and swells, leading to the ex ...
