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From electrochemical measurements at the interface of two immiscible electrolytes, the current at controlled potential is usually a linear function of the ion concentration in the aqueous phase. Surprisingly, a linear relationship between the current and t ...
Electrospray ionization mass spectrometry of neat ionic liquids does not require continuous sample injection and the presence of a molecular solvent facilitates analysis of the ionic liquid itself and dissolved analytes. ...
We study the dielectric susceptibility of liquid hydrogen chloride at a temperature of 313 K using ab initio molecular dynamics evolving, in a homogeneous electric field. For an evolution in absence of electric field, the calculated neutron structure facto ...
The invention concerns injectable bone filling cements, in particular hydraulic calcium phosphate cements, the latter being prepared from at least two initial liquid or pasty constituents comprising each a species reactive in solution or in suspension, the ...
This paper presents a three-dimensional, MODFLOW/MT3DMS- based reactive multicomponent transport model for saturated porous media. Based on a split-operator technique, the model, referred to as PHT3D, couples the transport simulator MT3DMS and the geochemi ...
The IR and Raman spectra and conformations of the ionic liquid 1-ethyl-3-methyl-1H-imidazolium tetrafluoroborate, [EMIM][BF4] (6), were analyzed within the framework of scaled quantum mechanics (SQM). It was shown that SQM successfully reproduced the spect ...
A review of the recent achievements in an understanding of the synthesis, soln. behavior, structure and bonding of the homopolyat. sulfur cations. A focus is put on the developments aimed to understand exptl. observations, i.e., quantum chem. calcns. of th ...
The solubility of hydrogen and the corresponding Henry coefficients for 11 ionic liquids have been determined in situ at 100 atm H-2 pressure and are much lower than expected; attempts to correlate the solubility of hydrogen in the ionic liquids with the r ...
Many low oxidation state transition metal (carbonyl) clusters are salts and are highly soluble in ionic liquids. Since many are also effective catalysts/precatalysts for hydrogenation reactions, we have conducted a catalytic study of these compounds in ion ...
Catalysts immobilised in ionic liquids have been analysed using electrospray ionisation ion trap mass spectrometry, which allows identification of the catalyst without contamination from the ionic liquid; additionally, a new ionic liquid containing the Mon ...
