Concept
Leaving group
Related publications (58)
Oxidative rearrangement of 1,1-disubstituted alkenes to ketones
Qian Wang, Jieping Zhu, Qiang Feng
The Wacker process, which is widely used to convert monosubstituted alkenes into the corresponding methyl ketones, is thought to proceed through a PdII/Pd0 catalytic cycle involving a b-hydride elimination step. This mechanistic scenario is inapplicable to ...
2023Mechanochemical synthesis of novel rutile-type high entropy fluorides for electrocatalysis
Seunghwa Lee, Kai Wang, Parvathy Anitha Sukkurji
Multicomponent rutile (P42/mnm) structured fluorides, containing 4 to 7 transition metals (Co, Cu, Mg, Ni, Zn, Mn, and Fe) in equiatomic ratios, were synthesized using a simple mechanochemical approach. The high entropy fluorides were characterized using d ...
2021Surface Reconstruction Engineering with Synergistic Effect of Mixed‐Salt Passivation Treatment toward Efficient and Stable Perovskite Solar Cells
Michael Graetzel, Shaik Mohammed Zakeeruddin, Yeonju Kim, Ulf Anders Hagfeldt, Filippo de Angelis, Hui-Seon Kim, Bowen Yang, Jiajia Suo
Surface passivation treatment is a widely used strategy to resolve trap-mediated nonradiative recombination toward high-efficiency metal-halide perovskite photovoltaics. However, a lack of passivation with mixture treatment has been investigated, as well a ...
2021Access to Vinyl Ethers and Ketones with Hypervalent Iodine Reagents as Oxy-Allyl Cation Synthetic Equivalents
We report an Umpolung strategy of enol ethers to generate oxy-allyl cation equivalents based on the use of hypervalent iodine reagents. Under mild basic conditions, the addition of nucleophiles to aryloxy-substituted vinylbenziodoxolone (VBX) reagents, eas ...
WILEY-V C H VERLAG GMBH2020