Publications related to SN2 reaction

Nucleophilic Reactivity of a Nitride-Bridged Diuranium(IV) Complex: CO2 and CS2 Functionalization

Marinella Mazzanti, Lucile Sylvie Danielle Chatelain, Marta Falcone

Thermolysis of the nitride-bridged diuranium(IV) complex Cs{(-N)U(OSi((OBu)-Bu-t)(3))(3)} (1) showed that the bridging nitride behaves as a strong nucleophile, promoting N-C bond formation by siloxide ligand fragmentation to yield an imido-bridged sil ...

2016

Rate Law Analysis of Water Oxidation and Hole Scavenging on a BiVO4 Photoanode

Florian Le Formal, Yimeng Ma

Spectroelectrochemical studies employing pulsed LED irradiation are used to investigate the kinetics of water oxidation on undoped dense bismuth vanadate (BiVO4) photoanodes under conditions of photoelectrochemical water oxidation and compare to those obta ...

Amer Chemical Soc2016

Design strategy for controlled natural aging in Al-Mg-Si alloys

William Curtin

This study presents a design strategy for Al-Mg-Si alloys to control natural aging. Recently, trace addition of Sn was shown to suppress natural aging for up to two weeks, which was explained by the strong trapping of vacancies to Sn atoms. Here we explore ...

Pergamon-Elsevier Science Ltd2016

Thermoelasticity of Fe3+- and Al-bearing bridgmanite: Effects of iron spin crossover

Matteo Cococcioni

We report ab initio (LDA + U-sc) calculations of thermoelastic properties of ferric iron (Fe3+)- and aluminum (Al)-bearing bridgmanite (MgSiO3 perovskite), the main Earth forming phase, at relevant pressure and temperature conditions and compositions. Thre ...

American Geophysical Union2016

Rate Law Analysis of Water Oxidation on a Hematite Surface

Michael Graetzel, Florian Le Formal, Stanley David Tilley

Water oxidation is a key chemical reaction, central to both biological photosynthesis and artificial solar fuel synthesis strategies. Despite recent progress on the structure of the natural catalytic site, and on inorganic catalyst function, determining th ...

American Chemical Society2015

Transforming Hybrid Organic Inorganic Perovskites by Rapid Halide Exchange

Michael Graetzel, Joachim Maier, Joël Teuscher, Norman Pellet

We report on rapid halide exchange in metal halide perovskite of the general formula MAPbX(3) (X = Cl, Br, or I). We find that when the perovskite is infiltrated in a mesoscopic scaffold, halide substitution on the perovskite lattice is strikingly fast, be ...

American Chemical Society2015

Capture and Release of CO2 in Monoethanolamine Aqueous Solutions: New Insights from First-Principles Reaction Dynamics

Wanda Andreoni, Fabio Pietrucci, Changru Ma

Aqueous,monoethanolamine (MEA) solution is commonly used for post-combustion carbon capture via chemical absorption. Extensive research has been carried out to characterize both uptake and release of carbon dioxide (CO2), with the aim of improving process ...

Amer Chemical Soc2015

Resonance Raman and Excitation Energy Dependent Charge Transfer Mechanism in Halide-Substituted Hybrid Perovskite Solar Cells

Ulf Anders Hagfeldt

Organo-metal halide perovskites (OMHPs) are materials with attractive properties for optoelectronics. They made a recent introduction in the photovoltaics world by methylammonium (MA) lead triiodide and show remarkably improved charge separation capabiliti ...

American Chemical Society2015

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SN2 reaction

Nucleophilic Reactivity of a Nitride-Bridged Diuranium(IV) Complex: CO2 and CS2 Functionalization

Rate Law Analysis of Water Oxidation and Hole Scavenging on a BiVO4 Photoanode

Key Players in I-DmoI Endonuclease Catalysis Revealed from Structure and Dynamics

Understanding the anomalous behavior of Vegard's law in Ce1-xMxO2 (M = Sn and Ti; 0 < x

Design strategy for controlled natural aging in Al-Mg-Si alloys

Thermoelasticity of Fe3+- and Al-bearing bridgmanite: Effects of iron spin crossover

Rate Law Analysis of Water Oxidation on a Hematite Surface

Transforming Hybrid Organic Inorganic Perovskites by Rapid Halide Exchange

Capture and Release of CO2 in Monoethanolamine Aqueous Solutions: New Insights from First-Principles Reaction Dynamics

Resonance Raman and Excitation Energy Dependent Charge Transfer Mechanism in Halide-Substituted Hybrid Perovskite Solar Cells

Graph Chatbot

Chat with Graph Search

Nucleophilic Reactivity of a Nitride-Bridged Diuranium(IV) Complex: CO2 and CS2 Functionalization

Understanding the anomalous behavior of Vegard's law in Ce1-xMxO2 (M = Sn and Ti; 0 < x

Rate Law Analysis of Water Oxidation and Hole Scavenging on a BiVO4 Photoanode

Design strategy for controlled natural aging in Al-Mg-Si alloys

Rate Law Analysis of Water Oxidation on a Hematite Surface

Key Players in I-DmoI Endonuclease Catalysis Revealed from Structure and Dynamics

Thermoelasticity of Fe3+- and Al-bearing bridgmanite: Effects of iron spin crossover

Transforming Hybrid Organic Inorganic Perovskites by Rapid Halide Exchange

Resonance Raman and Excitation Energy Dependent Charge Transfer Mechanism in Halide-Substituted Hybrid Perovskite Solar Cells

Capture and Release of CO2 in Monoethanolamine Aqueous Solutions: New Insights from First-Principles Reaction Dynamics