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In the discussion on the use of the surface Laplacian (SL) of the distribution of bioelectric potentials on the body surface, the question remained open whether a complete specification of the SL of the potential over the surface bounding a volume conducto ...
The voltage induced assembly and photoreactivity of cadmium selenide (CdSe) nanoparticles protected by mercaptosuccinic acid are studied at the polarisable interface between water and 1,2-dichloroethane electrolyte solutions. Cyclic voltammograms and admit ...
Electro-oxidn. of platinum film electrode deposited on yttria-stabilized zirconia (YSZ) is examd. in situ using potential programmed voltammetry at 450 DegC in oxygen contg. atm. Under prolonged anodic oxidn. different sorts of oxidized species are formed ...
The interface between two immiscible electrolyte solutions (ITIES), or liquid|liquid interface, provides a defect-free junction for fundamental studies of adsorption phenomena, heterogeneous charge transfer reactions, and phase-formation processes. Recent ...
Molecular dynamics (MD) simulations, performed with embedded atom potentials, are used to understand the formation of defects following displacement cascades in Ni. Different empirical potentials, presenting large differences in stacking fault energy (SFE) ...
Cytochrome c6A is a unique dithio-cytochrome of green algae and plants. It has a very similar core structure to that of bacterial and algal cytochromes c6 but is unable to fulfill the same function of transferring electrons from cytochrome f to photosystem ...
The heterodimer formed by electrostatic association of zinc(II) meso-tetrakis(N-methylpyridyl)porphyrin (ZnTMPyP) and zinc(II) meso-tetrakis(p-sulfonatophenyl)porphyrin (ZnTPPS) exhibits a strong affinity for the interface between water and 1,2-dichloroeth ...
The adsorption of ions at the interface between two immiscible electrolyte solutions (ITIES) is primarily controlled by the potential distribution across the interface, which in turn is influenced by the adsorption process. In the present paper, we simulat ...
Hexanethiolate monolayer-protected gold nanoclusters (MPCs) were used as redox quenchers at the polarizable water/1,2-dichloroethane (DCE) interface. Photocurrent responses originating from the heterogeneous quenching of photoexcited water soluble porphyri ...
The redox properties of monolayer-protected gold nanoclusters (MPCs) are considered from both the theoretical and experimental viewpoints. The “absolute standard redox potential” ([ ]abs) of MPCs is first derived from electrostatic considerations. A linear ...