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The reaction of the UO2+ precursor [(UO 2Py5)(KI2Py2)]n, with the potassium salt of the tetradentate aza β-diketiminate ligand L (L = 2-(4-tolyl)-1,3-bis(quinolyl)malondiiminate) affords the ...
This review provides an overview of smart chemistry developed and utilized in the last 5–10 years in polymer-based drug delivery nanomedicine. Smart chemistry not only facilitates the controlled drug loading in a highly specific manner, but also potentiall ...
Dodecaborates, i.e. the [B12H12]2- containing species, are often observed as main intermediates in the hydrogen sorption cycle of metal borohydrides, hindering rehydrogenation. In the decomposition process of Y(BH4)3, yttrium octahydrotriborate, i.e. Y(B3H ...
The iodouranium(iii) complex with two hydrotris(3,5-dimethylpyrazolyl) borate ligands is shown to adopt three closely related forms in the solid state. In addition to the previously reported structure for [U(TpMe2) 2I], in which one of the pyrazolyl rings ...
Review. Synthetic control over inorg. nanocrystals has made dramatic strides so that a great no. of binary and a few ternary or more complex compds. can now be prepd. with good control over size and phys. properties. Recently, chemists have tackled the lon ...
We study the spontaneous curving observed when a strip of tracing paper is deposited on a water surface. The differential swelling across the ribbon thickness leads to a curling of the sheet, with the curvature increasing to a maximum and then relaxing as ...
At EPFL, a strategy for organising scientific outreach activities has been developed and a programme comprising various measures and actions elaborated to promote science and technology among youngsters, especially young girls. As part of this programme, w ...
The polymeric complex [(NpO2Py5)(KI 2Py2)]n is prepared from dry "NpO 2Cl" by anion exchange with potassium iodide in pyridine affording the first convenient starting material for the development of NpO 2+ coordination chemistry in anhydrous organic media. ...
The development of molecular probes to visualize cellular processes is an important challenge in chemical biology. One possibility to create such cellular indicators is based on the selective labeling of proteins with synthetic probes in living cells. Over ...
Morphological computation can be loosely defined as the exploitation of the shape, material properties, and physical dynamics of a physical system to improve the efficiency of a computation. Morphological control is the application of morphological computi ...