Concept

Samarium

Related publications (48)

Subcomponent Self-Assembly of Rare-Earth Single-Molecule Magnets

A family of lanthanide complexes has been synthesized by the subcomponent self-assembly methodology. Molecular architectures, which were stable in solution and under ambient conditions, were designed by the in situ formation of ligands around lanthanide io ...

Amer Chemical Soc2013

Radioactive Europium-Chelate-Based Silica Nanoparticles as a Probe for Stability, Incorporation Efficiency and Trace Analysis

Marinella Mazzanti

Two luminescent terbium and europium lanthanide chelates were efficiently embedded into silica nanoparticles by using a reverse microemulsion process. The incorporation was achieved without covalent bonding between the lanthanide chelates and the silica ma ...

2013

Nonpareil Yb Behavior in YbMn6Ge6-xSnx

Marco Grioni

We investigate the temperature dependence of the Yb valence in YbMn6Ge1.8Sn4.2 and YbMn6Ge1.6Sn4.4 using resonant inelastic x-ray scattering experiments. Yb is found to be in an intermediate valent state in the whole investigated temperature range (10-450 ...

American Physical Society2013

Optimization of gadolinium-based MRI contrast agents for high magnetic‑field applications

Lothar Helm

The search for higher spatial resolution and better sensitivity stimulates the development of high-field (3 T) and ultrahigh field (>3 T) MRI scanners. Gadolinium-based MRI contrast agents, commercial ones used in clinics, as well as recently developed mor ...

2010

Lanthanide luminescence efficiency in eight- and nine-coordinate complexes: Role of the radiative lifetime

Anne-Sophie Chauvin, Svetlana Eliseeva

The photophysical parameters for the sensitization of metal-centred luminescence are analyzed in two series of complexes with tridentate and hexadentate ligands having NxOy chelating units. In particular, the radiative lifetime tau(rad) is experimentally e ...

Elsevier2010

Enhanced electrical conductivity of ultrafine-grained 8Y(2)O(3) stabilized ZrO2 produced by two-step sintering technique

Mehdi Mazaheri

Two-step sintering of nanocrystalline zirconia powder stabilized with 8 mol% yttria resulted in remarkable enhancement of the electrical conductivity and significant suppression of the accelerated grain growth. The electrical conductivity of the nearly ful ...

2010

Surprisingly Bright Near-Infrared Luminescence and Short Radiative Lifetimes of Ytterbium in Hetero-Binuclear Yb-Na Chelates

Rosario Scopelliti, Jean-Claude Bünzli, Frédéric Gumy

New heterobinuclear lanthanide complexes with benzoxazole-substituted 8-hydroxyquinolines, [Ln(ligand)2(μ-ligand)2Na] (Ln: Yb, Lu), have been prepared and their structure established by X-ray crystallography, 1H NMR spectroscopy, and photophysical studies. ...

2009

Multiple Frequency and Variable Temperature EPR study of Gd(III) polyaminocarboxylates: analysis and comparison of the magnetically dilute powder and the frozen solution spectra

André Merbach, Lothar Helm, Alain Borel

An Electron Paramagnetic Resonance (EPR) study of glasses and magnetically dilute powders of [Gd(DTPA)(H2O)]2−, [Gd(DOTA)(H2O)]-, and macromolecular Gd-P792 complexes was carried out at X-, Q-band and 240 GHz DTPA=diethylenetriaminepentaacetato; DOTA=1,4,7 ...

2009

On the lattice coherency of oxide particles dispersed in EUROFER97

Nadine Baluc, Robin Schäublin, Amuthan Ramar

Oxide dispersion strengthened steels based on the ferritic/martensitic steel EUROFER97 are developed. The reinforcing particles dispersed in the matrix of EUROFER97 are made of yttria and yttrium titanium oxides. Microstructure is investigated by transmiss ...

Elsevier2009

Determination of within-rod caesium and europium isotopic distributions in high burnup fuel rods through computerised gamma-ray emission tomography

Rakesh Chawla, Stefano Caruso, Fabian Jatuff

Computerised gamma-ray emission tomography has been applied to single PWR UO2 fuel rods, with pellet averaged burnups of 52, 71, 91 and 126 GWd/t respectively, for the determination of 134Cs, 137Cs and 154Eu internal radial distributions. State-of-the-art ...

Elsevier Science B.V.2009

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