Relations between heat capacitiesIn thermodynamics, the heat capacity at constant volume, , and the heat capacity at constant pressure, , are extensive properties that have the magnitude of energy divided by temperature. The laws of thermodynamics imply the following relations between these two heat capacities (Gaskell 2003:23): Here is the thermal expansion coefficient: is the isothermal compressibility (the inverse of the bulk modulus): and is the isentropic compressibility: A corresponding expression for the difference in specific heat capacities (intensive properties) at constant volume and constant pressure is: where ρ is the density of the substance under the applicable conditions.
Relativistic heat conductionRelativistic heat conduction refers to the modelling of heat conduction (and similar diffusion processes) in a way compatible with special relativity. In special (and general) relativity, the usual heat equation for non-relativistic heat conduction must be modified, as it leads to faster-than-light signal propagation. Relativistic heat conduction, therefore, encompasses a set of models for heat propagation in continuous media (solids, fluids, gases) that are consistent with relativistic causality, namely the principle that an effect must be within the light-cone associated to its cause.
English Engineering UnitsSome fields of engineering in the United States use a system of measurement of physical quantities known as the English Engineering Units. Despite its name, the system is based on United States customary units of measure. The English Engineering Units is a system of consistent units used in the United States. The set is defined by the following units, and definitive conversions to the International System of Units. Units for other physical quantities are derived from this set as needed.
Debye modelIn thermodynamics and solid-state physics, the Debye model is a method developed by Peter Debye in 1912 for estimating the phonon contribution to the specific heat (Heat capacity) in a solid. It treats the vibrations of the atomic lattice (heat) as phonons in a box, in contrast to the Einstein photoelectron model, which treats the solid as many individual, non-interacting quantum harmonic oscillators. The Debye model correctly predicts the low-temperature dependence of the heat capacity of solids, which is proportional to – the Debye T 3 law.
Polytropic processA polytropic process is a thermodynamic process that obeys the relation: where p is the pressure, V is volume, n is the polytropic index, and C is a constant. The polytropic process equation describes expansion and compression processes which include heat transfer. Some specific values of n correspond to particular cases: for an isobaric process, for an isochoric process. In addition, when the ideal gas law applies: for an isothermal process, for an isentropic process.
CalorimeterA calorimeter is an object used for calorimetry, or the process of measuring the heat of chemical reactions or physical changes as well as heat capacity. Differential scanning calorimeters, isothermal micro calorimeters, titration calorimeters and accelerated rate calorimeters are among the most common types. A simple calorimeter just consists of a thermometer attached to a metal container full of water suspended above a combustion chamber. It is one of the measurement devices used in the study of thermodynamics, chemistry, and biochemistry.
Specific volumeIn thermodynamics, the specific volume of a substance (symbol: ν, nu) is an intrinsic property of the substance, defined as the ratio of the substance's volume (V) to its mass (m). It is the reciprocal of density ρ (rho) and it is related to the molar volume and molar mass: The standard unit of specific volume is cubic meters per kilogram (m3/kg), but other units include ft3/lb, ft3/slug, or mL/g.
