Incendiary weapons, incendiary devices, incendiary munitions, or incendiary bombs are weapons designed to start fires or destroy sensitive equipment using fire (and sometimes used as anti-personnel weaponry), using materials such as napalm, thermite, magnesium powder, chlorine trifluoride, or white phosphorus. Though colloquially often known as bombs, they are not explosives but in fact are designed to slow the process of chemical reactions and use ignition rather than detonation to start or maintain the reaction. Napalm, for example, is petroleum especially thickened with certain chemicals into a 'gel' to slow, but not stop, combustion, releasing energy over a longer time than an explosive device. In the case of napalm, the gel adheres to surfaces and resists suppression.
Early thermal weapons
A range of early thermal weapons were utilized by ancient, medieval/post-classical and early modern armies, including hot pitch, oil, resin, animal fat and other similar compounds. Substances such as quicklime and sulfur could be toxic and blinding. Incendiary mixtures, such as the petroleum-based Greek fire, were launched by throwing machines or administered through a siphon. Sulfur- and oil-soaked materials were sometimes ignited and thrown at the enemy, or attached to spears, arrows or bolts, and fired by hand or machine. Some siege techniques—such as mining and boring—relied on combustibles and fire to complete the collapse of walls and structures.
Towards the latter part of the period, gunpowder was invented, which increased the sophistication of the weapons, starting with fire lances.
The first incendiary devices to be dropped during World War I fell on coastal towns in the east of England on the night of 18–19 January 1915. The small number of German bombs, also known as firebombs, were finned containers filled with kerosene and oil and wrapped with tar-covered rope. They were dropped from Zeppelin airships. On 8 September 1915, Zeppelin L-13 dropped a large number of firebombs, but even then the results were poor and they were generally ineffective in terms of the damage inflicted.