Publications related to Metal carbon dioxide complex

Electro- and photochemical H-2 generation by Co(ii) polypyridyl-based catalysts bearing ortho-substituted pyridines

Rosario Scopelliti, Euro Solari, Albert Ruggi, Vincent Artero, Fiorella Lucarini

Cobalt(II) complexes featuring hexadentate amino-pyridyl ligands have been recently discovered as highly active catalysts for the Hydrogen Evolution Reaction (HER), whose high performance arises from the possibility of assisting proton transfer processes v ...

ROYAL SOC CHEMISTRY2023

Improving time-resolution and sensitivity of in situ X-ray photoelectron spectroscopy of a powder catalyst by modulated excitation

Davide Ferri, Oliver Kröcher, Filippo Buttignol

Ambient pressure X-ray photoelectron spectroscopy (APXPS) is a powerful tool to characterize the surface structure of heterogeneous catalysts in situ. In order to improve the time resolution and the signal-to-noise (S/N) ratio of photoemission spectra, we ...

ROYAL SOC CHEMISTRY2023

C-C bond activation enabled by dyotropic rearrangement of Pd(iv) species

Qian Wang, Jieping Zhu, Hua Wu, Jian Cao

The weak carbon-metal bond combined with the kinetic inertness of the carbon-carbon bond renders metal-catalysed C-C bond activation to be highly challenging. Most of the reported C-C bond activation methodologies involve strain-releasing cleavage of small ...

NATURE RESEARCH2021

Colloidal-ALD Grown Hybrid Shells Nucleate via a Ligand–Precursor Complex

David Lyndon Emsley, Raffaella Buonsanti, Anna Loiudice, Michael Allan Hope, Ona Segura Lecina, Kevin Rossi, Snaedis Björgvinsdóttir, Amrit Venkatesh

Colloidal atomic layer deposition (c-ALD) enables the growth of hybrid organic/inorganic oxide shells with tunable thickness at the nanometer scale around ligand-functionalized inorganic nanoparticles (NPs). This recently developed method has demonstrated ...

2021

Copper(ii) complexes with tridentate halogen-substituted Schiff base ligands: synthesis, crystal structures and investigating the effect of halogenation, leaving groups and ligand flexibility on antiproliferative activities

Rosario Scopelliti

To investigate the effect of different halogen substituents and leaving groups and the flexibility of ligands on the anticancer activity of copper complexes, sixteen copper(ii) complexes with eight different tridentate Schiff-base ligands containing pyridi ...

ROYAL SOC CHEMISTRY2021

Interfacial Effect between Aluminum-Based Complex Hydrides and Nickel-Containing Porous Carbon Sheets

Andreas Züttel, Emad Oveisi, Heena Yang, Mo Li, Youngdon Ko

Supported aluminum-based complex hydrides (alanates) were investigated in view of their interaction at the interface. Nickel-containing porous carbon sheets (Ni-PCSs) were combined with various alanates, resulting in a decrease of the decomposition tempera ...

AMER CHEMICAL SOC2020

High-Valent Nickel Promoted by Atomically Embedded Copper for Efficient Water Oxidation

Jun Li, Ning Wang, Yun Liu, Bo Zhang

Efficient and low-cost electrocatalysts for oxygen evolution reaction (OER), particularly in neutral conditions, are of significant importance for renewable energy technologies such as CO2 reduction and seawater splitting electrolysis. High-valent transiti ...

AMER CHEMICAL SOC2020

Tailoring Chiral Cyclopentadienyl Rhodium(III) Catalysts for Enantioselective Alkenyl C-H functionalizations

Coralie Danielle Annick Duchemin

Chiral cyclopentadienyl (Cpx) metal complexes have empowered the developement of challenging asymmetric C(sp2)-H activation transformations. However the preparation of competent atropchiral Cpx ligands is long and tedious. Moreover the range of application ...

EPFL2020

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Metal carbon dioxide complex

Electro- and photochemical H-2 generation by Co(ii) polypyridyl-based catalysts bearing ortho-substituted pyridines

Complexation Strategies towards Challenging Group 9 Metal Cyclopentadienyl Scaffolds

Improving time-resolution and sensitivity of in situ X-ray photoelectron spectroscopy of a powder catalyst by modulated excitation

C-C bond activation enabled by dyotropic rearrangement of Pd(iv) species

Colloidal-ALD Grown Hybrid Shells Nucleate via a Ligand–Precursor Complex

Copper(ii) complexes with tridentate halogen-substituted Schiff base ligands: synthesis, crystal structures and investigating the effect of halogenation, leaving groups and ligand flexibility on antiproliferative activities

Synthesis of Chiral Cyclopentadienyl Complexes and Applications Towards C-H Functionalization

Interfacial Effect between Aluminum-Based Complex Hydrides and Nickel-Containing Porous Carbon Sheets

High-Valent Nickel Promoted by Atomically Embedded Copper for Efficient Water Oxidation

Tailoring Chiral Cyclopentadienyl Rhodium(III) Catalysts for Enantioselective Alkenyl C-H functionalizations

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Synthesis of Chiral Cyclopentadienyl Complexes and Applications Towards C-H Functionalization

Complexation Strategies towards Challenging Group 9 Metal Cyclopentadienyl Scaffolds

Tailoring Chiral Cyclopentadienyl Rhodium(III) Catalysts for Enantioselective Alkenyl C-H functionalizations

High-Valent Nickel Promoted by Atomically Embedded Copper for Efficient Water Oxidation

Electro- and photochemical H-2 generation by Co(ii) polypyridyl-based catalysts bearing ortho-substituted pyridines

Improving time-resolution and sensitivity of in situ X-ray photoelectron spectroscopy of a powder catalyst by modulated excitation

C-C bond activation enabled by dyotropic rearrangement of Pd(iv) species

Copper(ii) complexes with tridentate halogen-substituted Schiff base ligands: synthesis, crystal structures and investigating the effect of halogenation, leaving groups and ligand flexibility on antiproliferative activities

Colloidal-ALD Grown Hybrid Shells Nucleate via a Ligand–Precursor Complex

Interfacial Effect between Aluminum-Based Complex Hydrides and Nickel-Containing Porous Carbon Sheets