Publications related to Metal carbonyl

CO2 induced phase transitions in diamine-appended metal-organic frameworks

Using a combination of density functional theory and lattice models, we study the effect of CO2 adsorption in an amine functionalized metal-organic framework. These materials exhibit a step in the adsorption isotherm indicative of a phase change. The press ...

Royal Soc Chemistry2015

Metal Complexes as MRI Contrast Enhancement Agents

André Merbach, Lothar Helm, Eva Jakab Toth

Magnetic resonance imaging is one of the most efficient diagnostic modalities in clinical radiology and biomedical research. To enhance image contrast, paramagnetic complexes, mainly Gd3+ chelates, are used. Today, around one third of all medical MR images ...

Elsevier2015

Cyanide Single-Molecule Magnets Exhibiting Solvent Dependent Reversible "On" and "Off" Exchange Bias Behavior

Jan Gui-Hyon Dreiser

The syntheses, structures, and magnetic properties of four new complex salts, (PPN){Mn-III(salphen)(MeOH)[M-III(CN)(6)]} 7MeOH (Mn2M 7MeOH) (M = Fe, Ru, Os and Co; PPN+ = bis(triphenylphosphoranylidene)ammonium cation; H2salphen = N,N'-bis(salicyliden ...

American Chemical Society2015

Intramolecular palladium-catalyzed alkene carboalkynylation

Jérôme Waser, Stefano Nicolai, Peter Swallow

Carbocycles are essential building blocks for the synthesis of natural and synthetic bioactive compounds. Herein, we report the first example of palladium-catalyzed intramolecular carboalkynylation of non-activated olefins. Using activated carbonyl compoun ...

Elsevier2015

Reconstitution of [Fe]-hydrogenase using model complexes

Xile Hu, Matthew Wodrich, Tao Xu, Dafa Chen

[Fe]-Hydrogenase catalyses the reversible hydrogenation of a methenyltetrahydromethanopterin substrate, which is an intermediate step during the methanogenesis from CO2 and H-2. The active site contains an iron-guanylylpyridinol cofactor, in which Fe2+ is ...

Nature Publishing Group2015

CS2 activation at uranium(III) siloxide ate complexes: the effect of a Lewis acidic site

Marinella Mazzanti, Julie Renée Michelle Andrez

Multimetallic cooperative binding of heteroallenes provides an attractive route to their activation, but the reduction of CS2 at heterobimetallic sites, associating an electron-rich metal with a main group Lewis acid has not been explored. Here we show tha ...

Royal Soc Chemistry2015

Mimicking Enzymatic Active Sites on Surfaces for Energy Conversion Chemistry

Klaus Kern, Magalí Alejandra Lingenfelder, Sebastian Stepanow

Metal organic supramolecular chemistry on surfaces has matured to a point where its underlying growth mechanisms are well understood and structures of defined coordination environments of metal atoms can be synthesized in a controlled and reproducible proc ...

Amer Chemical Soc2015

Cyclic Hypervalent Iodine Reagents and Iron Catalysts: The Winning Team for Late-Stage C-H Azidation

Jérôme Waser, Maria Victoria Vita

1+1=3: by combining the exceptional properties of benziodoxolone reagents and iron catalysts, Sharma and Hartwig have achieved an important breakthrough for the late-stage C-Hazidation of complex molecules. Nevertheless, moderate yields and selectivities w ...

Wiley-Blackwell2015

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Metal carbonyl

Synthesis and spectroscopy of anionic tridentate benzimidazole-pyridine carboxylate and tetrazolate chromophore ligands

CO2 induced phase transitions in diamine-appended metal-organic frameworks

Metal Complexes as MRI Contrast Enhancement Agents

Assembly and photocarrier dynamics of heterostructured nanocomposite photoanodes from multicomponent colloidal nanocrystals

Cyanide Single-Molecule Magnets Exhibiting Solvent Dependent Reversible "On" and "Off" Exchange Bias Behavior

Intramolecular palladium-catalyzed alkene carboalkynylation

Reconstitution of [Fe]-hydrogenase using model complexes

CS2 activation at uranium(III) siloxide ate complexes: the effect of a Lewis acidic site

Mimicking Enzymatic Active Sites on Surfaces for Energy Conversion Chemistry

Cyclic Hypervalent Iodine Reagents and Iron Catalysts: The Winning Team for Late-Stage C-H Azidation

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Chat with Graph Search

Cyanide Single-Molecule Magnets Exhibiting Solvent Dependent Reversible "On" and "Off" Exchange Bias Behavior

Metal Complexes as MRI Contrast Enhancement Agents

Cyclic Hypervalent Iodine Reagents and Iron Catalysts: The Winning Team for Late-Stage C-H Azidation

Synthesis and spectroscopy of anionic tridentate benzimidazole-pyridine carboxylate and tetrazolate chromophore ligands

Assembly and photocarrier dynamics of heterostructured nanocomposite photoanodes from multicomponent colloidal nanocrystals

Mimicking Enzymatic Active Sites on Surfaces for Energy Conversion Chemistry

Reconstitution of [Fe]-hydrogenase using model complexes

CS2 activation at uranium(III) siloxide ate complexes: the effect of a Lewis acidic site

CO2 induced phase transitions in diamine-appended metal-organic frameworks

Intramolecular palladium-catalyzed alkene carboalkynylation