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Under common processing conditions, both dilute and complex concentrated alloys are often realized as random alloys, with no correlation in the occupancy of lattice sites by the constituent atom types. The current thesis primary addresses two problems in r ...
Determination of the levels of heavy metal ions would support assessment of sources and pathways of water pollution. However, traditional spatial assessment by manual sampling and off-site detection in the laboratory is expensive and time-consuming and req ...
Mineralogy, chemistry and spatial distribution of phyllomanganates, found in abundance at the bottom of thick Ni-laterite deposits, were established on dislocated vein-infillings showing banded and fibrous patterns (i.e. colloforms with rows of tiny boxwor ...
Crystallization timescales in subvolcanic systems and the consequences of interaction between ascending magmas and gases remain largely unconstrained, as do links between these processes and monitoring signals at restless volcanoes. We apply diffusion chro ...
Accurately constraining the formation and evolution of the lunar magnesian suite is key to understanding the earliest periods of magmatic crustal building that followed accretion and primordial differentiation of the Moon. However, the origin and evolution ...
Transition-metal-catalyzed hydrosilylation of olefins is one of the most important methods for the preparation of organosilicon compounds, which have broad applications in both synthetic and material chemistry. For decades, precious metals, principally pla ...
Directed Cp*Rh-III-catalyzed carbon-hydrogen (C-H) bond functionalizations have evolved as a powerful strategy for the construction of heterocycles. Despite their high value, the development of related asymmetric reactions is largely lagging behind due to ...
Planetesimal were the first planetary objects to form in the solar system, which later grew to make the proto-planets. Most of these bodies were differentiated as a result of internal heating. Several differentiated bodies have, then, been accreted followi ...
Volcanic eruptions result from complex interplay of magmatic processes including the ascent and storage of magma in the crust, volatile exsolution and crystallization. The dynamics of crystallization in shallow subvolcanic systems and the consequences of i ...
Production of methanol (MeOH) from CO2 is strongly desired as a key chemical feedstock and a fuel. However, the conventional process requires elevated temperature and pressure, and high temperature restricts the productivity of MeOH due to equilibrium limi ...