Concept

Hexamethylbenzene

Related publications (12)

FB-ECDA: Fragment-based Electronic Coupling Decomposition Analysis for Organic Amorphous Semiconductors

We present a fragment-based decomposition analysis tool (FB-ECDA) for the electronic coupling of charge transfer processes. This tool provides insight on the sophisticated relationship between molecular packing, electronic coupling, and the molecular trans ...

AMER CHEMICAL SOC2020

Synthesis and Characterization of Coordination Cages Based on Clathrochelate Metalloligands

Giacomo Cecot

The work presented in this thesis focused on the synthesis and characterization of new metalloligands based on iron(II) clathrochelate complexes. Clathrochelates can be functionalized peripherally with donor groups capable of coordinating metal ions. The s ...

EPFL2019

Chiral Cyclopentadienyls: Enabling Ligands for Asymmetric Rh(III)-Catalyzed C-H Functionalizations

Nicolai Cramer, Baihua Ye

Transition-metal catalyzed C-H functionalizations became a complementary and efficient bond-forming strategy over the past decade. In this respect, Cp*Rh(III) complexes have emerged as powerful catalysts for a broad spectrum of reactions giving access to s ...

American Chemical Society2015

Templating Approach Towards Lamellar Carbon Nanomaterials from Oligo(phenylene) Amphiphiles

Dragana Paripovic

Templating approaches based on the self-assembly of block-copolymers represent a powerful tool for the preparation of ordered carbon-containing nanomaterials. Combining such strategies with the use of well-defined amphiphilic precursors with sp2-carbon-ric ...

EPFL2014

A Synthetic Entry into the Taiwaniaquinoids Based on a Biogenetic Hypothesis: Total Synthesis of (-)-Taiwaniaquinone H

Rosario Scopelliti, Karl Gademann

(Chemical Equation Presented) Less carbon: Following a biogenetic proposal, the unusual 6-5-6 carbon skeleton of C19 taiwaniaquinoids was obtained by an intramolecular benzilic acid rearrangement from a C20 precur-sor. A protecting-group-free total synthes ...

2010

Rational Tuning of Melting Entropies for Designing Luminescent Lanthanide-Containing Thermotropic Liquid Crystals at Room Temperature

Jean-Claude Bünzli, Frédéric Gumy, Annina Aebischer

The connection of twelve peripheral and divergent dodecyloxy chains to a central tridentate aromatic binding unit provides the dodecacatenar ligand L11, for which room- temperature mesomorphism is detected. An enthalpically unbalanced large melting entropy ...

2007

Development of Ruthenium Antitumor Drugs that Overcome Multidrug Resistance Mechanisms

Paul Joseph Dyson, Wee Han Ang, Andrew Douglas Phillips, Claudine Scolaro, Gianni Sava

Organometallic ruthenium(II) complexes of the general formula [Ru(η6-p-cymene)Cl2(L)] and [Ru(η6-p-cymene)Cl(L)2][BPh4] with modified phenoxazine- and anthracene-based multidrug resistanc ...

2007

Synthèses, structures et applications catalytiques de nouveaux complexes polynucléaires

Sébastien Gauthier

Various methods for the synthesis of bimetallic complexes, in which two different metal fragments which are connected by two or three halogeno bridges, are reported. The reactions are usually fast and give rise to structurally defined products in quantitat ...

EPFL2006

A nearly planar water sheet sandwiched between strontium-imidazolium carboxylate coordination polymers

Paul Joseph Dyson, Zhaofu Fei, Dongbin Zhao

The crystal structure of a strontium-imidazolium polymeric material obtained from the reaction of zwitterionic 1,3-bis(carboxymethyl)-imidazolium with SrCO3 (2:1) in water is reported. The compound crystallized in the orthorhombic space group Pcc2 with a = ...

2005

Analysis of Aromatic Delocalization: Individual Molecular Orbital Contributions to Nucleus-Independent Chemical Shifts

Individual MO (MO) contributions to the magnetic shielding of atoms as well as to the nucleus-independent chem. shifts (NICS) of arom. compds. can be computed by the widely used gauge-including AO (GIAO) method. Detailed analyses of magnetic shielding MO-N ...

2003

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