Publications related to Homogeneity and heterogeneity

Tandem Hydroformylation-Aldol Condensation Reaction Enabled by Zn-MOF-74

The tandem hydroformylation-aldol condensation (tandem HF-AC) reaction offers an efficient synthetic route to the synthesis of industrially relevant products. The addition of Zn-MOF-74 to the cobalt-catalyzed hydroformylation of 1-hexene enables tandem HF- ...

WILEY-V C H VERLAG GMBH2023

Understanding the mechanisms of adhesive wear for heterogeneous materials through atomistic simulations

Jean-François Molinari, Antonio Joaquin Garcia Suarez, Sacha Zenon Wattel

When two rough surfaces slide against each other, two main behaviors can be observed at the asperity level: A ductile behavior where the asperities tend to smooth out or a brittle behavior where the asperities detach and form debris. Recently, a critical l ...

ELSEVIER2022

Electrochemically CO2 conversion using homogeneous and nanostructured heterogeneous Ru (II) electrocatalysts

Farzaneh Fadaei Tirani

The reduction of carbon dioxide to desirable products is an urgent goal in favour of the environment, the energy-cycle and mankind. We report the electrochemical reduction of CO2 to carbon monoxide by means of the ho-mogeneous electrocatalyst (1), [Ru(bpy) ...

ELSEVIER SCI LTD2022

Impact of dipole-dipole interactions on motility-induced phase separation

Ignacio Pagonabarraga Mora, Elena Sesé Sansa

We present a hydrodynamic theory for systems of dipolar active Brownian particles which, in the regime of weak dipolar coupling, predicts the onset of motility-induced phase separation (MIPS), consistent with Brownian dynamics (BD) simulations. The hydrody ...

ROYAL SOC CHEMISTRY2022

Validation of axial void profile measured by neutron noise techniques in CROCUS

Andreas Pautz, Vincent Pierre Lamirand, Mathieu Hursin, Oskari Ville Pakari, Pavel Frajtag

Recently a joint project has been carried out between the Paul Scherrer Institut, the Ecole Polytechnique Federale de Lausanne and swissnuclear, an industrial partner, in order to determine the axial void distribution in a channel installed in the reflecto ...

2021

An in-situ 3D micro-XRD investigation of water uptake by alkali-silica-reaction (ASR) product

Mahdieh Shakoorioskooie

The ASR products in concrete have various chemical compositions. It is yet unclear whether and how these products develop micro-expansion upon moisture ingress. This paper presents a 3D in-situ observation of the crystallography and volume change of an ASR ...

PERGAMON-ELSEVIER SCIENCE LTD2021

Metal-organic frameworks as kinetic modulators for branched selectivity in hydroformylation

Berend Smit, Gerald Bauer, Daniele Ongari, Davide Tiana, Mohamed Tarik

Finding heterogeneous catalysts that are superior to homogeneous ones for selective catalytic transformations is a major challenge in catalysis. Here, we show how micropores in metal-organic frameworks (MOFs) push homogeneous catalytic reactions into kinet ...

2020

Imaging the Heterogeneity of the Oxygen Evolution Reaction on Gold Electrodes Operando: Activity is Highly Local

Sylvie Roke, Arianna Marchioro, Igor Nahálka

Understanding the mechanism of the oxygen evolution reaction (OER), the oxidative half of electrolytic water splitting, has proven challenging. Perhaps the largest hurdle has been gaining experimental insight into the active site of the electrocatalyst use ...

2020

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Homogeneity and heterogeneity

Tandem Hydroformylation-Aldol Condensation Reaction Enabled by Zn-MOF-74

Understanding the mechanisms of adhesive wear for heterogeneous materials through atomistic simulations

Electrochemically CO2 conversion using homogeneous and nanostructured heterogeneous Ru (II) electrocatalysts

Impact of dipole-dipole interactions on motility-induced phase separation

Validation of axial void profile measured by neutron noise techniques in CROCUS

An in-situ 3D micro-XRD investigation of water uptake by alkali-silica-reaction (ASR) product

Mapping of Chemical Heterogeneity at Surfaces with High-Throughput Wide-Field Second Harmonic Microscopy

Polygenic modelling of treatment effect heterogeneity

Metal-organic frameworks as kinetic modulators for branched selectivity in hydroformylation

Imaging the Heterogeneity of the Oxygen Evolution Reaction on Gold Electrodes Operando: Activity is Highly Local

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Validation of axial void profile measured by neutron noise techniques in CROCUS

Polygenic modelling of treatment effect heterogeneity

An in-situ 3D micro-XRD investigation of water uptake by alkali-silica-reaction (ASR) product

Metal-organic frameworks as kinetic modulators for branched selectivity in hydroformylation

Tandem Hydroformylation-Aldol Condensation Reaction Enabled by Zn-MOF-74

Electrochemically CO2 conversion using homogeneous and nanostructured heterogeneous Ru (II) electrocatalysts

Impact of dipole-dipole interactions on motility-induced phase separation

Understanding the mechanisms of adhesive wear for heterogeneous materials through atomistic simulations

Mapping of Chemical Heterogeneity at Surfaces with High-Throughput Wide-Field Second Harmonic Microscopy

Imaging the Heterogeneity of the Oxygen Evolution Reaction on Gold Electrodes Operando: Activity is Highly Local