Publications related to Vinyl group

trans-Mutation at Gold(III): A Mechanistic Study of a Catalytic Acetylene Functionalization via a Double Insertion Pathway

Gabor Laurenczy

The Au(III) complex Au(tpy)(OAcF)2 (OAcF = OCOCF3; tpy = 2-(p-tolyl)pyridine) catalyzes the anti addition of trifluoroacetic acid (HOAcF) to acetylene to furnish vinyl trifluor- oacetate. The Au(III) vinyl complex Au(tpy)(OAcF)(CHCHOAcF) (vinyl group bond ...

American Chemical Society2017

Mild synthesis of mercaptonitriles from vinyl nitriles and their cyclization reactions

Frank Nüesch, Antonia Neels

Thiol-ene addition of thioacetic acid A is widely used in the synthesis of thiols from vinyl precursors, but so far has not been conducted on non-conjugated vinyl nitriles. The challenge when vinyl nitriles are used is to selectively conduct the thiol-ene ...

Royal Soc Chemistry2016

Synthesis of Oxazolidin-2-ones by Oxidative Coupling of Isonitriles, Phenyl Vinyl Selenone, and Water

Qian Wang, Jieping Zhu, Thomas Bertrand Pascal Marie Buyck, Delphine Pasche

Reaction of alkyl isocyanides, phenyl vinyl selenone, and water in the presence of a catalytic amount of Cs2CO3 afforded oxazolidin-2-ones in good yields. This unprecedented heteroannulation process created four chemical bonds in a single operation with th ...

Wiley-Blackwell2016

Selectivity Control in Palladium-Catalyzed Alcohol Oxidation through Selective Blocking of Active Sites

Davide Ferri, Oliver Kröcher, Di Wang

Stabilized metal nanoparticles (NPs) have received wide interest in a number of liquid-phase catalytic transformations, but the role of the capping/protective agent is still debated. Operando attenuated total reflection infrared (ATR-IR) spectroscopy enabl ...

American Chemical Society2016

Strategy to Optimize the Biological Activity of Arene Ruthenium Metalla-Assemblies

Paul Joseph Dyson, Tina Riedel

Three new dinuclear arene ruthenium metalla-clips of the general formula [(p-cymene)(2)Ru2Cl2(mu-L)] have been prepared from {(p-cymene)(2)Ru2Cl2(p-Cl)(2)] and H2L organic linkers (H2La = diethyl-1,2-diazeneclicarboxylate, H2Lb = N,N'-bis(2-hydroxyethyl)ox ...

Amer Chemical Soc2014

Isocyanoacetates as Synthetic Platform Towards Natural Products and Biologically Relevant Scaffolds

Thomas Bertrand Pascal Marie Buyck

My PhD work started with the development of a racemic access to trigonoliimine B, an hexacyclic alkaloid isolated in 2010. After having explored different strategies, we reported a 7-step synthesis of this natural product. This synthesis features a challen ...

EPFL2014

Functional, Hyperbranched Polyesters Via Baylis-Hillman Polymerization

Harm-Anton Klok, Frederik Roman Wurm, Sanhao Ji

Hyperbranched polyesters are among the most common hyperbranched polymers. One of the interesting features of hyperbranched polyesters is that they contain unreacted hydroxyl and carboxylic acid groups at the linear and terminal structural units, which can ...

2012

Formal Homo-Nazarov and Other Cyclization Reactions of Activated Cyclopropanes

Jérôme Waser, Fides Benfatti, Tanguy Jean Daniel Saget, Filippo De Simone

The Nazarov cyclization of divinyl ketones gives access to cyclopentenones. Replacing one of the vinyl groups by a cyclopropane leads to a formal homo-Nazarov process for the synthesis of cyclohexenones. In contrast to the Nazarov reaction, the cyclization ...

2011

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Vinyl group

trans-Mutation at Gold(III): A Mechanistic Study of a Catalytic Acetylene Functionalization via a Double Insertion Pathway

A facile synthetic strategy to polysiloxanes containing sulfonyl side groups with high dielectric permittivity

Mild synthesis of mercaptonitriles from vinyl nitriles and their cyclization reactions

Synthesis of Oxazolidin-2-ones by Oxidative Coupling of Isonitriles, Phenyl Vinyl Selenone, and Water

Selectivity Control in Palladium-Catalyzed Alcohol Oxidation through Selective Blocking of Active Sites

Synthesis of silicone elastomers containing trifluoropropyl groups and their use in dielectric elastomer transducers

Strategy to Optimize the Biological Activity of Arene Ruthenium Metalla-Assemblies

Isocyanoacetates as Synthetic Platform Towards Natural Products and Biologically Relevant Scaffolds

Functional, Hyperbranched Polyesters Via Baylis-Hillman Polymerization

Formal Homo-Nazarov and Other Cyclization Reactions of Activated Cyclopropanes

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Selectivity Control in Palladium-Catalyzed Alcohol Oxidation through Selective Blocking of Active Sites

A facile synthetic strategy to polysiloxanes containing sulfonyl side groups with high dielectric permittivity

trans-Mutation at Gold(III): A Mechanistic Study of a Catalytic Acetylene Functionalization via a Double Insertion Pathway

Strategy to Optimize the Biological Activity of Arene Ruthenium Metalla-Assemblies

Synthesis of Oxazolidin-2-ones by Oxidative Coupling of Isonitriles, Phenyl Vinyl Selenone, and Water

Functional, Hyperbranched Polyesters Via Baylis-Hillman Polymerization

Mild synthesis of mercaptonitriles from vinyl nitriles and their cyclization reactions

Formal Homo-Nazarov and Other Cyclization Reactions of Activated Cyclopropanes

Synthesis of silicone elastomers containing trifluoropropyl groups and their use in dielectric elastomer transducers

Isocyanoacetates as Synthetic Platform Towards Natural Products and Biologically Relevant Scaffolds