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Concept
Bloch's theorem
Summary
In condensed matter physics, Bloch's theorem states that solutions to the Schrödinger equation in a periodic potential can be expressed as plane waves modulated by periodic functions. The theorem is named after the physicist Felix Bloch, who discovered the theorem in 1929. Mathematically, they are written
where is position, is the wave function, is a periodic function with the same periodicity as the crystal, the wave vector is the crystal momentum vector, is Euler's number, and is the imaginary unit.
Functions of this form are known as Bloch functions or Bloch states, and serve as a suitable basis for the wave functions or states of electrons in crystalline solids.
Named after Swiss physicist Felix Bloch, the description of electrons in terms of Bloch functions, termed Bloch electrons (or less often Bloch Waves), underlies the concept of electronic band structures.
These eigenstates are written with subscripts as , where is a discrete index, called the band index, which is present because there are many different wave functions with the same (each has a different periodic component ). Within a band (i.e., for fixed ), varies continuously with , as does its energy. Also, is unique only up to a constant reciprocal lattice vector , or, . Therefore, the wave vector can be restricted to the first Brillouin zone of the reciprocal lattice without loss of generality.
The most common example of Bloch's theorem is describing electrons in a crystal, especially in characterizing the crystal's electronic properties, such as electronic band structure. However, a Bloch-wave description applies more generally to any wave-like phenomenon in a periodic medium. For example, a periodic dielectric structure in electromagnetism leads to photonic crystals, and a periodic acoustic medium leads to phononic crystals. It is generally treated in the various forms of the dynamical theory of diffraction.
Suppose an electron is in a Bloch state
where u is periodic with the same periodicity as the crystal lattice.
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