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Hydrogenation of the water-soluble [{RuCl2(mtppms)(2)}(2)] (mtppms = monosulfonated triphenylphosphine) was studied in aqueous solutions in the presence of excess mtppms both with H-2 and with aqueous HCOONa. Depending on the reductant, the pH and H-2 pres ...
Cavitation bubbles, when correctly tuned, may provide interesting mechanical and chemical effects to their surroundings owing to their violent collapse. Such an event may produce high-speed liquid jetting, extreme heating, as well as pressures of thousands ...
On the path to functional graphene electronics, suitable templates for chemical vapor deposition (CVD) growth of high -mobility graphene are of great interest. Among various substrates, hexagonal boron nitride (h-BN) has established itself as one of the mo ...
The new water-soluble ruthenium-nitrosyl complexes [RuCl3(NO)(TPPMS)(2)] and [RuCl3(NO)(TPPTS)(2)] were synthetized and characterized by IR, H-1 and P-31 NMR spectroscopies. The NO stretching frequencies, nu(NO) = 1870 cm(-1) (TPPMS) and 1883 cm(-1) (TPPTS ...
We have performed a series of co-compression experiments on Au, Pt, Mo, MgO and NaCl to extend internally consistent pressure calibration and characterize shear strength of pressure media to 2.5 Mbar. Measured unit cell volumes of calibrants show differenc ...
The two known Me- and allyl-substituted 1H-imidazol-3-ium bromides 1 and 2, respectively, were converted to the corresponding BF4- and BPh4- salts 3-6 (Scheme 1). Compounds 3 and 4 were liquids at ambient temperature. Reaction of 1 or 2 with [PdCl2] afford ...
This is the first study of the effect of pressure on transition metal dichalcogenides (TMDs) intercalated by atoms that order magnetically. Co0.33NbS2 is a layered system where the intercalated Co atoms order antiferromagnetically at T-N = 26 K at ambient ...
The water-sol. ruthenium(II) complexes [Cp'RuX(PTA)2]Y and [CpRuCl(PPh3)(mPTA)]OTf (Cp' = Cp, Cp*, X = Cl and Y = nil; or X = MeCN and Y = PF6; PTA = 1,3,5-triaza-7-phosphaadamantane; mPTA = 1-methyl-1,3,5-triaza-7-phosphaadamantane) were used as catalyst ...