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Treatment of RO3SC6H4Me-4 with R1MgBr in THF over Li2CuCl4 at -78 Deg with slowly raising the temp. to room temp. gave, in good yields, the derivs. RR1 (R = e.g. Et, Ph, cyclohexyl, or octyl; R1 = Et, CMe3, Ph, cyclohexyl). [on SciFinder (R)] ...
We studied and compared the hydrodeoxygenation (HDO) and depolymerization of aldehyde-stabilized lignin and 4-propylguaiacol (PG), a model lignin monomer. We demonstrated by liquid phase adsorption that PG HDO catalyzed by Ru/C can be achieved in isooctane ...
H-ZSM-5 zeolite has been shown to be an active catalyst for the synthesis of polyoxymethylene dimethyl ethers (OME). However, we demonstrated – by passivation of the zeolite's external surface – that the reaction rate is limited due to severe internal diff ...