Concept
Matrix mechanics
Related concepts (23)
Moyal bracket
In physics, the Moyal bracket is the suitably normalized antisymmetrization of the phase-space star product. The Moyal bracket was developed in about 1940 by José Enrique Moyal, but Moyal only succeeded in publishing his work in 1949 after a lengthy dispute with Paul Dirac. In the meantime this idea was independently introduced in 1946 by Hip Groenewold. The Moyal bracket is a way of describing the commutator of observables in the phase space formulation of quantum mechanics when these observables are described as functions on phase space.
Adiabatic invariant
A property of a physical system, such as the entropy of a gas, that stays approximately constant when changes occur slowly is called an adiabatic invariant. By this it is meant that if a system is varied between two end points, as the time for the variation between the end points is increased to infinity, the variation of an adiabatic invariant between the two end points goes to zero. In thermodynamics, an adiabatic process is a change that occurs without heat flow; it may be slow or fast.
Stark effect
The Stark effect is the shifting and splitting of spectral lines of atoms and molecules due to the presence of an external electric field. It is the electric-field analogue of the Zeeman effect, where a spectral line is split into several components due to the presence of the magnetic field. Although initially coined for the static case, it is also used in the wider context to describe the effect of time-dependent electric fields. In particular, the Stark effect is responsible for the pressure broadening (Stark broadening) of spectral lines by charged particles in plasmas.