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The design of delivery vehicles that are stable in circulation but can be activated by exogenous energy sources is challenging. Our goals are to validate new imaging methods for the assessment of particle stability, to engineer stable and activatable parti ...
Three new cation-cation complexes of pentavalent uranyl, stable with respect to the disproportionation reaction, have been prepared from the reaction of the precursor [(UO 2py 5)(KI 2py 2)] n (1) with the Schiff base ligands salen 2-, acacen 2-, and saloph ...
Results of a theoretical study on the properties of Ir4 clusters in the gas–phase and on oxide surfaces are presented. The work is based on density functional theory (DFT) within the generalized gradient approximation (GGA) and ultrasoft pseudopotentials. ...
The recent experimental programme conducted in the PROTEUS research reactor at the Paul Scherrer Institute (PSI) has concerned detailed investigations of advanced light water reactor (LWR) fuels. More than fifteen different configurations of the multi-zone ...
A program is described, which allows the intensity contributions from naturally occurring heavy isotopes to be eliminated from the mass spectrometric ions of an artificially labelled compound. This allows the accurate measurement of the isotopomer distribu ...
This paper presents the results of an effort to label calcium carbonates formed by marine organisms with stable isotopes to obtain information about the biomineralization processes. The growing skeleton of the scleractinian coral Porites porites was labele ...
The lithium isotope compositions (Li-7/Li-6) and Li/Ca ratios of shallow-water and deep-sea corals (Porites lutea, Cladocora caespitosa, Lophelia pertusa and Desmophyllum cristagalli) were measured using a Cameca ims 1270 ion microprobe. The two C. caespit ...
In this paper, a novel model for single-bit internal quantizer Sigma Delta-modulators is presented. It is shown that this model can be used for an exact stability prediction of these systems. Furthermore, it is explained how the necessary computations can ...
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A novel experimental set-up was used to study superstable (magic) Ba-C-60 and K-C-60 compound clusters. The most stable systems observed cannot be rationalized by simple electronic or by geometrical shell filling arguments. Annealing the clusters past the ...
(La,Sr)FeO3 mixed conducting perovskites are considered as interesting candidates for oxygen separation membranes but they suffer from limited structural stability in a large oxygen partial pressure (pO2) gradient, because of their propensity for chemical ...