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The chemistry of divalent lanthanides has generated increasing interest in the past years due to their redox properties and unique reaction pathways. Notably, molecular complexes of low-valent lanthanides have been shown to be suitable one-electron reducta ...
The development of new catalytic methods for organic synthesis is a critical endeavour in order to obviate the economic and ecological drawbacks of stoichiometric organic synthesis. While catalysis can offer significant advantages in terms of atom-economy, ...
The atmosphere is considered as an important external nutrient source for the marine environment, especially in remote ocean waters or the oligotrophic Mediterranean Sea. Phosphorus (P) is a critical nutrient affecting primary productivity in large areas o ...
For effective water quality management and policy development, spatial variability in the mean concentrations and dynamics of riverine water quality needs to be understood. Using water chemistry (calcium, electrical conductivity, nitrate-nitrite, soluble r ...
The analysis of concentration-discharge (C-Q) relationships provides useful information on the processes controlling the mobilization and delivery of chemical elements into streams as well as biogeochemical transformations in river networks. Previous metri ...
The tightening emission regulations have led to the development of commercial DOCs with zoned or layered formulations allowing to cover a wide range of functionalities (i.e. CO, HC and NO oxidation as well as HC or NOx trap). Aging phenomena in such comple ...
We report the influence of N-heterocyclic carbenes (NHCs) on the hydrolysis of a diphosphene TerP?PTer (1; Ter = 2,6-Mes(2)C(6)H(3); Mes = 2,4,6-Me3C6H2), a phosphorus-analogue of an alkene. The diphosphene 1 itself is completely inert towards water. Howev ...
In the Mekong delta, inland-based shrimp breeding is a profitable activity requiring significant inflow of high quality freshwater. In turn, discharge of substantial loads of poor quality effluents causes salinization and eutrophication of adjacent water b ...
The synthesis of five half sandwich ruthenium(II) trichlorogermyl complexes of the type [(η6-Arene)Ru(PR3)Cl(GeCl3)] (PR3 = Phosphane and phosphite ligands; Arene = p-cymene or C6H5-OC2H4OH) is reported: [(η6-p-cymene)Ru(P(OMe)3)Cl(GeCl3)] (1), [(η6-p-cyme ...
Controlling phosphorus is fundamental to limit the risk of eutrophication of continental aquatic ecosystems. Integrated modelling of its concentration in the aquatic continuum requires specific tools for water bodies. However, although simple static empiri ...
