Positronium (Ps) is a system consisting of an electron and its anti-particle, a positron, bound together into an exotic atom, specifically an onium. Unlike hydrogen, the system has no protons. The system is unstable: the two particles annihilate each other to predominantly produce two or three gamma-rays, depending on the relative spin states. The energy levels of the two particles are similar to that of the hydrogen atom (which is a bound state of a proton and an electron). However, because of the reduced mass, the frequencies of the spectral lines are less than half of those for the corresponding hydrogen lines.
The mass of positronium is 1.022 MeV, which is twice the electron mass minus the binding energy of a few eV. The lowest energy orbital state of positronium is 1S, and like with hydrogen, it has a hyperfine structure arising from the relative orientations of the spins of the electron and the positron.
The singlet state, _para-positronium, with antiparallel spins (S = 0, Ms = 0) is known as para-positronium (p-Ps). It has a mean lifetime of 0.12ns and decays preferentially into two gamma rays with energy of 511keV each (in the center-of-mass frame). Para-positronium can decay into any even number of photons (2, 4, 6, ...), but the probability quickly decreases with the number: the branching ratio for decay into 4 photons is 1.439e-6.
Para-positronium lifetime in vacuum is approximately
The triplet states, 3S1, with parallel spins (S = 1, Ms = −1, 0, 1) are known as ortho-positronium (o-Ps), and have an energy that is approximately 0.001 eV higher than the singlet. These states have a mean lifetime of 142.05ns, and the leading decay is three gammas. Other modes of decay are negligible; for instance, the five-photons mode has branching ratio of ≈e-6.
Ortho-positronium lifetime in vacuum can be calculated approximately as:
However more accurate calculations with corrections to O(α2) yield a value of 7.040us−1 for the decay rate, corresponding to a lifetime of 142ns.