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Concept
Thermal energy
Summary
The term "thermal energy" is used loosely in various contexts in physics and engineering. It can refer to several different well-defined physical concepts. These include the internal energy or enthalpy of a body of matter and radiation; heat, defined as a type of energy transfer (as is thermodynamic work); and the characteristic energy of a degree of freedom, , in a system that is described in terms of its microscopic particulate constituents (where denotes temperature and denotes the Boltzmann constant).
In thermodynamics, heat is energy transferred to or from a thermodynamic system by mechanisms other than thermodynamic work or transfer of matter, such as conduction, radiation, and friction. Heat refers to a quantity transferred between systems, not to a property of any one system, or "contained" within it. On the other hand, internal energy and enthalpy are properties of a single system. Heat and work depend on the way in which an energy transfer occurred, whereas internal energy is a property of the state of a system and can thus be understood without knowing how the energy got there.
The internal energy of a body can change in a process in which chemical potential energy is converted into non-chemical energy. In such a process, the thermodynamic system can change its internal energy by doing work on its surroundings, or by gaining or losing energy as heat. It is not quite lucid to merely say that 'the converted chemical potential energy has simply become internal energy'. It is, however, convenient and more lucid to say that 'the chemical potential energy has been converted into thermal energy'. Such thermal energy may be viewed as a contributor to internal energy or to enthalpy, thinking of the contribution as a process without thinking that the contributed energy has become an identifiable component of the internal or enthalpic energies. The thermal energy is thus thought of as a 'process entity' rather than as an 'enduring physical entity'. This is expressed in ordinary traditional language by talking of 'heat of reaction'.
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