Concept

Uranium-238

Related publications (65)

A Route to Stabilize Uranium(II) and Uranium(I) Synthons in Multimetallic Complexes

Rosario Scopelliti, Marinella Mazzanti, Ivica Zivkovic

Herein, we report the redox reactivity of a multimetallic uranium complex supported by triphenylsiloxide (−OSiPh3) ligands, where we show that low valent synthons can be stabilized via an unprecedented mechanism involving intramolecular ligand migration. T ...

2023

Implementing Multi-Electron Transfer Strategies in Uranium Chemistry

Dieuwertje Katelijn Modder

In the last decades, the activation of small molecules has attracted increasing attention for their use as cheap and abundant feedstock. Low-oxidation state uranium complexes have displayed high reactivity towards small molecules thanks to their unique pro ...

EPFL2023

Characteristics of the spent nuclear fuel (SNF) are typically calculated, requiring validation a priori. The validation process relies on the difference between calculations and measurements, namely the bias. Usually, predicting the bias based on benchmark ...

EPFL2022

Systematic investigations of uranium carbide composites oxidation from micro- to nano-scale: Application to waste disposal

Nhât-Tân Vuong

The production of radioisotope beams at the ISOLDE (Isotope Separator OnLine DEvice) facility at CERN is achieved by irradiating target materials (e.g. uranium carbides and metal foils) with protons. The materials are usually operated at temperatures above ...

EPFL2021

A Hybrid Approach to Neutron Transport with Thermal-hydraulic Feedback for Reactor Transient Analysis

Alexander Aures

Understanding the time-dependent behaviour of a nuclear reactor following an intended or unintended change of the reactor conditions is of crucial importance to the safe operation of nuclear reactors. Safety evaluations of nuclear reactors involve the anal ...

EPFL2021

Structural performance and mechanical properties investigation of spent nuclear fuel rods under static and dynamic bending loads

Efstathios Vlassopoulos

Currently, most Spent Nuclear Fuel (SNF) is kept safely in storage either at on-site facilities or at centralized interim storage sites. Moreover, many countries face delays in implementing their waste management programmes for SNF and high-level waste dis ...

EPFL2021

Uranium Isotope Fractionation during the Anoxic Mobilization of Noncrystalline U(IV) by Ligand Complexation

Rizlan Bernier-Latmani, Ashley Richards Brown

Uranium (U) isotopes are suggested as a tool to trace U reduction. However, noncrystalline U(IV), formed predominantly in near-surface environments, may be complexed and remobilized using ligands under anoxic conditions. This may cause additional U isotope ...

2021

Preliminary design and analysis of Liquid Fuel Molten Salt Reactor using multi-physics code GeN-Foam

Carlo Fiorina

In this study, a hypothetical fast spectrum Liquid Fuel Molten Salt Reactor (LFMSR) core is modeled using the multiphysics C++ code GeN-Foam (General Nuclear Foam). GeN-Foam is based on OpenFOAM, a C++ opensource library for solution of continuum mechanics ...

ELSEVIER SCIENCE SA2020

Role of Iron Sulfide Phases in the Stability of Noncrystalline Tetravalent Uranium in Sediments

Rizlan Bernier-Latmani, Luca Loreggian

Uranium (U) in situ bioremediation has been investigated as a cost-effective strategy to tackle U contamination in the subsurface. While uraninite was believed to be the only product of bioreduction, numerous studies have revealed that noncrystalline U(IV) ...

AMER CHEMICAL SOC2020

Nanoscale mechanism of UO2 formation through uranium reduction by magnetite

Rizlan Bernier-Latmani, Barbora Bártová, Zezhen Pan

Uranium (U) is a ubiquitous element in the Earth's crust at similar to 2 ppm. In anoxic environments, soluble hexavalent uranium (U(VI)) is reduced and immobilized. The underlying reduction mechanism is unknown but likely of critical importance to explain ...

2020

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