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Both first-principles molecular dynamics and theoretical X-ray absorption spectroscopy have been used to investigate the aqueous solvation of cations in 0.5 M MgCl(2), CaCl(2), and NaCl solutions. We focus here on the species-specific effects that Mg(2+), ...
Superparamagnetic iron oxide nanoparticles (SPIONs) were coated with polyethylenimine. Here, we briefly describe the synthesis as well as DNA:PEI:SPION complexes and the characterization of the compounds according to their particle size, zeta-potential, mo ...
The first part of this study consists in the investigation of the evaporation and the condensation rate of H2O in the presence of different types of ice in a low pressure flow reactor. The second part of the present work reports the study of chlorine activ ...
A model showing the importance of the parameters characterizing ion transport through geometrically defined nanoslits filled with electrolyte is presented. A conductance plateau sin log-log scaled at low salt concentrations in the nanometer-sized apertures ...
A description of ion transport through geometrically defined nanoslits is presented. It is characterized by the effective surface charge density and was obtained by impedance spectroscopy measurements of electrolytes with different physico-chemical propert ...
The HOCl heterogeneous reaction on frozen natural (NSS) and recrystallized (RSS) sea salt KCl and NaCl solutions was studied using a low pressure flow reactor in order to measure the uptake coefficient gamma and products of reaction The HOCl sample used in ...
Oldenbourg Wissenschaftsverlag GmbH, De Gruyter2010
The oxidation of dimethyl sulfide (DMS, CH3SCH3) in the atmosphere could influence climate by affecting cloud condensation nuclei concentrations and cloud properties. This work focuses on elucidating the importance of DMS-cloud intera ...
Recently, it has been suggested that Darcy's Law might not be applicable for modelling miscible, density-dependent flow in porous media. To investigate this, three sets of careful laboratory column experiments were performed on coarse and medium sands, con ...
Pollution can undergo long-range transport and impact the tropospheric chemistry thousands of kilometers downwind from the source region. Recently, there is interest in the intercontinental transport (ICT) of pollution between the main industrial regions o ...
A numerical study was conducted to investigate the influence of tides on the fate of terrestrially-derived BTEX discharging through an unconfined aquifer to coastal waters. Previous studies have revealed that tide-induced seawater circulations create an ac ...