Concept

Isomerase

Related publications (32)

Chemistry of a-aminonitriles. Aldomerization of glycolaldehyde phosphate to rac-hexose 2,4,6-triphosphates and (in presence of formaldehyde) rac-pentose 2,4-diphosphates: rac-allose 2,4,6-triphosphate and rac-ribose 2,4-diphosphate are the main reaction products

Glycoaldehyde phosphate aldomerizes in aq. NaOH to a product mixt. contg. the racemates of two diastereomeric tetrose 2,4-diphosphates and 8 hexose 2,4,5-triphosphates. The aldomerization of glycoaldehyde in the presence of formaldehyde is a variant of the ...

1990

Synthèse totale asymétrique des L-allose, L-talose, D-allonojirimycine et désoxypolyoxine C

Derivatives of 7-oxabicyclo[2.2.l]hept-5-en-2-yl ("naked sugars") are readily available through Diels-Alder cycloaddition of furan to an appropriate dienophile. Several methods allow one to obtain these molecules in optically pure form. They have been used ...

EPFL1990

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