Concept

Diiron nonacarbonyl

Related publications (8)

A Strategy to Conjugate Bioactive Fragments to Cytotoxic Diiron Bis(cyclopentadienyl) Complexes

Paul Joseph Dyson, Mouna Hadiji, Silvia Schoch, Sarah Alexandra Pais Pereira

A series of bioactive molecules were synthesized from the condensation of aspirin or chlorambucil with terminal alkynes bearing alcohol or amine substituents. Insertion of the resulting alkynes into the iron-carbyne bond of readily accessible diiron bis(cy ...

AMER CHEMICAL SOC2021

Diiron Complexes with a Bridging Functionalized Allylidene Ligand: Synthesis, Structural Aspects, and Cytotoxicity

Paul Joseph Dyson, Lucinda Kate Batchelor, Silvia Schoch

Regio- and stereoselective nucleophilic attack of cyanide (from NBu4CN) to cationic diiron vinyliminium compounds [Fe2Cp2(CO)(mu-CO){mu-eta(1):eta(3)-C-(R')C(R '')-CNMe2}]CF3SO3 ([1a-f]CF3SO3) affords the nitrile-aminoallylidene derivatives 2a-f in good to ...

AMER CHEMICAL SOC2020

Anticancer Potential of Diiron Vinyliminium Complexes

Paul Joseph Dyson, Lucinda Kate Batchelor, Silvia Schoch

Although ferrocene derivatives have attracted considerable attention as possible anticancer agents, the medicinal potential of diiron complexes has remained largely unexplored. Herein, we describe the straightforward multigram-scale synthesis and the antip ...

WILEY-V C H VERLAG GMBH2019

CO2 Binding and Induced Structural Collapse of a Surface-Supported Metal-Organic Network

Klaus Kern, Sebastian Stepanow, Christopher Seiji Kley

Extensive efforts have been directed toward identifying catalytic material composites for efficiently transforming CO2 into valuable chemicals. Within this long-standing scientific challenge, the investigation of model systems is of particular interest to ...

Amer Chemical Soc2016

Functionalization of Open Two-Dimensional Metal-Organic Templates through the Selective Incorporation of Metal Atoms

Klaus Kern, Sebastian Stepanow, Christopher Seiji Kley

Surface-confined molecular networks can serve as templates to steer the adsorption and organization of secondary ligands, metal atoms, and clusters. Here, the incorporation of Ni atoms and clusters into open two-dimensional robust metal-organic templates s ...

Amer Chemical Soc2013

Selective Binding of O(2) over N(2) in a Redox-Active Metal-Organic Framework with Open Iron(II) Coordination Sites

Berend Smit, Wendy Lee Queen

The air-free reaction between FeCl2 and H4dobdc (dobdc4- = 2,5-dioxido-1,4-benzenedicarboxylate) in a mixt. of N,N-dimethylformamide (DMF) and methanol affords Fe2(dobdc)·4DMF, a metal-org. framework adopting the MOF-74 (or CPO-27) structure type. The deso ...

2011

Investigation of low-dimensional supramolecular architectures by low-temperature scanning tunneling microscopy

Sylvain Clair

In this thesis we report investigations on supramolecular architectures assembled at well-defined metal surfaces. Supramolecular chemistry is dedicated to the study and use of non-covalent interactions to build highly organized molecular arrangements, aimi ...

EPFL2004

Synthèse et dynamique intramoléculaire du cluster dodécacarbonyle triiridiumrhodium et de ses dérivés

The goal of our work was the synthesis and studies on the reactivity and intramolecular dynamics of new classes of mixed clusters of the type Ir3Rh(CO)12. In total 17 derivatives of this compound have been synthesized, with ligands such as halogenides, mon ...

EPFL1993

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