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The two-step electron transfer during bacterial reduction of UVI to UIV is typically accompanied by mass-independent fractionation of the 238U and 235U isotopes, whereby the heavy isotope accumulates in the reduced product. However, the role of the UV inte ...
2024
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Solid-state photochemically induced dynamic nuclear polarization (photo-CIDNP) is a nuclear magnetic resonance spectroscopy technique in which nuclear spin hyperpolarization is generated upon optical irradiation of an appropriate donor-acceptor system. Unt ...
Amer Chemical Soc2024
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Why are materials with specific characteristics more abundant than others? This is a fundamental question in materials science and one that is traditionally difficult to tackle, given the vastness of compositional and configurational space. We highlight he ...
Nature Portfolio2024
To date, the vast majority of studies seeking to link discharge to solute concentrations have been based on representations of fluid age distributions in watersheds that are time-invariant. As increasingly detailed spatial and temporal datasets become avai ...
New Haven2023
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The C-19 stream is the most metal-poor stellar system ever discovered, with a mean metallicity [Fe/H] = -3.38 +/- 0.06. Its low metallicity dispersion (sigma([Fe/H]) < 0.18 at the 95 per cent confidence level) and variations in sodium abundances strongly s ...
OXFORD UNIV PRESS2022
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Dynamic nuclear polarisation (DNP) of solids doped with high-spin metal ions, such as Gd3+, is a useful strategy to enhance the nuclear magnetic resonance (NMR) sensitivity for these samples. Spin diffusion can relay polarisation throughout a sample, which ...
ACADEMIC PRESS INC ELSEVIER SCIENCE2023
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The coral-algal symbiosis is maintained by a constant and limited nitrogen availability in the holobiont. Denitrifiers, i.e., prokaryotes reducing nitrate/nitrite to dinitrogen, could contribute to maintaining the nitrogen limitation in the coral holobiont ...
2022
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Uranium isotopic signatures can be harnessed to monitor the reductive remediation of subsurface contamination or to reconstruct paleo-redox environments. However, the mechanistic underpinnings of the isotope fractionation associated with U reduction remain ...
2022
Measuring the isotopic composition of trace Zr in presolar stardust grains allows us to study the environment of slow neutron-capture nucleosynthesis in asymptotic giant branch stars. Here, we present a newly characterized Zr resonance ionization scheme th ...
2022
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Original data pertaining to the manuscript 'Persistence of the isotopic signature of pentavalent uranium in magnetite' published in Environmental Science and Technology by Zezhen Pan, Yvonne Roebbert, Aaron Beck, Barbora Bartova, Tonya Vitova, Stefan Weyer ...