Publications related to Catalyst poisoning

Solvent- and catalyst-free reduction of CO2 with ammonia borane

Andreas Züttel, Youngdon Ko, Liping Zhong

Ammonia borane (AB) has been extensively studied as a solid-state hydrogen storage material. On the other hand, its reactivity with CO2 is still unclear, especially in the solid state. By carefully controlling the CO2 pressure and temperature, AB efficient ...

Cambridge2024

Quantifying mass transport limitations in a microfluidic CO2 electrolyzer with a gas diffusion cathode

Sophia Haussener, Venu Gopal Agarwal

A gas diffusion electrode (GDE) based CO2 electrolyzer shows enhanced CO2 transport to the catalyst surface, significantly increasing current density compared to traditional planar immersed electrodes. A two-dimensional model for the cathode side of a micr ...

2024

Morphology and Transport Characterization of Catalyst Layers for CO2 Reduction

Sophia Haussener, Francesca Lorenzutti

Gas diffusion electrodes (GDEs) help to reduce transport limitations in devices for electrochemical CO2 reduction. Homogenized modeling of such devices requires input of morphological characteristics and effective transport properties of the porous structu ...

2023

Three-dimensional nanoimaging of fuel cell catalyst layers

Vasiliki Tileli, Robin Pierre Alain Girod, Timon Lazaridis

Catalyst layers in proton exchange membrane fuel cells consist of platinum-group-metal nanocatalysts supported on carbon aggregates, forming a porous structure through which an ionomer network percolates. The local structural character of these heterogeneo ...

NATURE PORTFOLIO2023

Catalyst Aggregate Size Effect on the Mass Transport Properties of Non-Noble Metal Catalyst Layers for PEMFC Cathodes

Vasiliki Tileli, Robin Pierre Alain Girod, Michele Bozzetti, Yen-Chun Chen, Secil Unsal

Non-noble metal catalysts (NNMCs) are regarded as a promising alternative to the costly Pt-based materials required to catalyze the oxygen reduction reaction (ORR) in proton exchange membrane fuel cell (PEMFC) cathodes. However, the large diversity of NNMC ...

ELECTROCHEMICAL SOC INC2023

Insights into Electrocatalyst Transformations Studied in Real Time with Electrochemical Liquid-Phase Transmission Electron Microscopy

Vasiliki Tileli, Tzu-Hsien Shen, Robin Pierre Alain Girod

The value of operando and in situ characterization methodologies for understanding electrochemical systems under operation can be inferred from the upsurge of studies that have reported mechanistic insights into electrocatalytic processes based on such mea ...

Washington2023

Genetic Algorithms for the Discovery of Homogeneous Catalysts

Rubén Laplaza Solanas, Anne-Clémence Corminboeuf, Puck Elisabeth van Gerwen, Alexandre Alain Schöpfer, Simone Gallarati

In this account, we discuss the use of genetic algorithms in the inverse design process of homogeneous catalysts for chemical transformations. We describe the main components of evolutionary experiments, specifically the nature of the fitness function to o ...

2023

Construction of Fe3O4 bridged Pt/g-C3N4 heterostructure with enhanced solar to fuel conversion

Michael Graetzel, Shaik Mohammed Zakeeruddin

In this study, we report the effects of co-catalysts of Pt nanoparticles and Fe3O4 clusters on photocatalytic behaviors of g-C3N4 (CN) and the use of the resulting photocatalyst for CO2 photoreduction to solar fuels in a flow reactor operated at room-tempe ...

ELSEVIER2022

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Catalyst poisoning

Heterogeneous catalysis via light-heat dual activation: A path to the breakthrough in C1 chemistry

Solvent- and catalyst-free reduction of CO2 with ammonia borane

Quantifying mass transport limitations in a microfluidic CO2 electrolyzer with a gas diffusion cathode

Morphology and Transport Characterization of Catalyst Layers for CO2 Reduction

Electron imaging of gas diffusion electrodes for proton exchange membrane fuel cells

Three-dimensional nanoimaging of fuel cell catalyst layers

Catalyst Aggregate Size Effect on the Mass Transport Properties of Non-Noble Metal Catalyst Layers for PEMFC Cathodes

Insights into Electrocatalyst Transformations Studied in Real Time with Electrochemical Liquid-Phase Transmission Electron Microscopy

Genetic Algorithms for the Discovery of Homogeneous Catalysts

Construction of Fe3O4 bridged Pt/g-C3N4 heterostructure with enhanced solar to fuel conversion

Graph Chatbot

Chat with Graph Search

Genetic Algorithms for the Discovery of Homogeneous Catalysts

Quantifying mass transport limitations in a microfluidic CO2 electrolyzer with a gas diffusion cathode

Solvent- and catalyst-free reduction of CO2 with ammonia borane

Insights into Electrocatalyst Transformations Studied in Real Time with Electrochemical Liquid-Phase Transmission Electron Microscopy

Construction of Fe3O4 bridged Pt/g-C3N4 heterostructure with enhanced solar to fuel conversion

Morphology and Transport Characterization of Catalyst Layers for CO2 Reduction

Electron imaging of gas diffusion electrodes for proton exchange membrane fuel cells

Heterogeneous catalysis via light-heat dual activation: A path to the breakthrough in C1 chemistry

Three-dimensional nanoimaging of fuel cell catalyst layers

Catalyst Aggregate Size Effect on the Mass Transport Properties of Non-Noble Metal Catalyst Layers for PEMFC Cathodes