Concept
Borate
Related publications (21)
Surfactant-free synthesis of mesoporous and hollow silica nanoparticles with an inorganic template
A surfactant-free synthesis of mesoporous and hollow silica nanoparticles is reported in which boron acts as the templating agent. Using such a simple and mild procedure as a treatment with water, the boron-rich phase is selectively removed, affording meso ...
2009(CsCl)2M(VO3)2 (M = Mn, Cu): Two new salt-inclusion meta-vanadates exhibiting channel structures with 5 and 14-membered-ring windows
Employing salt-inclusion chem., we have developed a new class of hybrid solids based on transition-metal-contg. silicate, phosphate, and arsenate systems which have resulted in a large no. of novel solids that exhibit fascinating nanostructures of magnetic ...
American Chemical Society2006The bora-ene reaction of sulfur dioxide and prop-2-ene-1-boronic esters. New route to sulfoxides
Pierre Vogel, Adrien Keith Lawrence, Maris Turks
A new one-pot synthesis of sulfoxides is presented. It involves the bora-ene reaction of sulfur dioxide and prop-2-ene-1-boronic esters, giving mixed anhydrides of sulfinic and boric acids. The latter react chemoselectively at the sulfur center with Grigna ...
2006Pressure-Induced Chemical Decomposition and Structural Changes of Boric Acid
Philip Pattison, Vladimir Dmitriev
A combined synchrotron X-ray diffraction, Raman scattering, and infrared spectroscopy study of the pressure-induced changes in H3BO3 to 10 GPa revealed a new high-pressure phase transition between 1 and 2 GPa followed by chemical decomposition into cubic H ...
2006Transient response method for characterization of active sites in HZSM-5 with low content of iron during N2O decomposition
The surface active Fe-sites in HZSM-5 with low content of iron (
2004Active Sites in HZSM-5 with Low Fe-content for the Formation of Surface Oxygen by Decomposing N2O: Is Every Deposited Oxygen Active?
Surface-active centers were detected in HZSM-5 with a low content of iron (
2003Electrochemical preparation of peroxodisulfuric acid using boron doped diamond thin film electrodes
Christos Comninellis, Pierre-Alain Michaud
The authors have studied the electrochem. oxidn. of H2SO4 on B-doped synthetic diamond electrodes (BDD) obtained by hot filament CVD on p-Si. High current efficiency for H2SO4 oxidn. to peroxodisulfuric acid can be achieved in concd. H2SO4 (>2M) at moderat ...
2002New boron-oxygen layer in the structure of barium hydrodecaborate Ba-5[B20O33(OH)(4)]center dot H2O
Gervais Chapuis, Alla Arakcheeva
The crystal structure of the new synthetic compound Ba-5[B20O33(OH)(4)] . H2O was established by the methods of X-ray diffraction (a Stoe IPDS diffractometer, lambda MoKalpha, 1860 independent reflections, anisotropic refinement, R = 1.95%, localization of ...
2000Arsenic adsorption and oxidation at manganite surfaces. 1. Method for simultaneous of determination of adsorbed and dissolved arsenic species
Arsenic occurs in the +III oxidation state as a metastable species in oxic waters. Under oxic conditions, As(III) is both more mobile in natural waters and less efficiently removed by water treatment processes than As(V). Other oxidants, however, can react ...
2000High-Pressure And High-Temperature Raman-Spectroscopy Of End-Member Garnets - Pyrope, Grossular And Andradite
The effect of pressure (up to 22 GPa) and temperature (to 1300 K) on the Raman spectra has been measured for pyrope, grossular and andradite garnets. No phase changes were observed and all Raman modes increase or decrease linearly with pressure and tempera ...
1992