Concept

Diphosphorus

Related publications (4)

The Solvent Effect on H2O2 Generation at Room Temperature Ionic Liquid|Water Interface

H2O2 is a versatile chemical and can be generated by the oxygen reduction reaction (ORR) in proton donor solution in molecular solvents or room temperature ionic liquids (IL). We investigated this reaction at interfaces formed by eleven hydrophobic ILs and ...

2021

Cooperative Effect of Monopodal Silica-Supported Niobium Complex Pairs Enhancing Catalytic Cyclic Carbonate Production

David Lyndon Emsley, Aaron James Rossini, Jeremie Pelletier

Recent discoveries highlighted the activity, and the intrig-uing, mechanistic features of NIDCl5 as a molecular catalyst for the cycloaddffion, of CO2 and epoxides under ambient cooditions. This hag inSpired the preparation, of novel silica-supported Nb sp ...

American Chemical Society2015

Dinitrogen dissociation on an isolated surface tantalum atom

David Lyndon Emsley

Both industrial and biochemical ammonia syntheses are thought to rely on the cooperation of multiple metals in breaking the strong triple bond of dinitrogen. Such multimetallic cooperation for dinitrogen cleavage is also the general rule for dinitrogen red ...

AMER ASSOC ADVANCEMENT SCIENCE2007

The [3+2] cycloaddition of diphenyldiazomethane and ethyl diazoacetate with itaconic anhydride. A new access to spiranic cyclopropane derivatives

Christophe Roussel

The reaction of itaconic anhydride with N2:CHCO2Et or Ph2C:N2 gave the expected spiro-derivs., which spontaneously rearranged; specifically, the adduct from Ph2C:N2 loses a dinitrogen mol., yielding a spirocyclopropane related to the known 5-azaspiro[2.4]h ...

2002

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