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Inlining is used in many different ways in programming languages: some languages use it as a compiler-directive solely for optimization, some use it as a metaprogramming feature, and others lay their design in-between. This paper presents inlining through ...
N-Enoxyimides have become attractive substrates for novel catalytic transformations, yet their tedious multi-step synthesis hampers full exploitation of their synthetic potential. We report a gold(I)-catalyzed protocol to access N-enoxyimides from simple a ...
2019
Programming languages are increasingly compiled to multiple runtimes, each featuring their own rich structures such as their object model.
Furthermore, they need to interact with other languages targeting said runtimes.
A language targeting only one runtim ...
EPFL2018
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Chiral sulfoximines with stereogenic sulfur atoms are promising motifs in drug discovery. We report an efficient method to access chiral sulfoximines through a C-H functionalization based kinetic resolution. A rhodium(III) complex equipped with a chiral Cp ...
Asymmetric metal-catalyzed C-H functionalization is a powerful strategy for the rapid generation of complex target molecules from simple precursors. While aryl (pseudo) halides have been used as electrophilic substrates in enantioselective Pd(0)-catalyzed ...
Various unsupervised learning algorithms including GMM, Birch, Mean- Shift, K-means and DBSCAN were used to cluster the image and depth sensor data. However, it was not possible to fit the clusters on each objects quite separately in as much as data are too ...
Asymmetric metal-catalyzed C-H functionalization has enjoyed great success as a powerful strategy for the rapid construction of elaborate structures from simple precursors. For example, aryl (pseudo)halides have been extensively employed as electrophilic s ...
We report the oxyalkynylation of thiiranes and thietanes using ethynylbenziodoxolone reagents (EBXs) to readily access functionalized building blocks bearing an alkynyl, a benzoate, and an iodide group. The reaction proceeds with high atom efficiency most ...