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The experimental lineshapes of the carboxyl and methyl carbon resonances of fully C-13 enriched L-Alanine are studied in detail at different MAS frequencies and decoupling field strengths. Complex lineshapes at intermediate spinning speeds were explained b ...
The experimental performance of the phase modulated decoupling schemes SDROOPY-1 and SPINAL64 is investigated for heteronuclear dipolar decoupling in solid-state magic-angle-spinning nuclear magnetic resonance (NMR), in comparison with existing decoupling ...
Spin-state selection in solid-state NMR is demonstrated, using similar pulse sequences as used in liquid-state NMR. The different transitions of all three carbon resonances in fully C-13-labeled L-alanine are separated in different spectra. By selecting sp ...
The reactivity of phenolic compounds can be drastically affected by the electronic nature of substituents and by their positions in the aromatic ring. In this work, structure effect on the photoreactivity via TiO2 catalysis is studied using several substit ...
In this Letter we present a framework for the use of continuously phase modulated radio-frequency pulses for heteronuclear decoupling in NMR of Liquid Crystals. Within this framework, we found new sets of heteronuclear decoupling sequences using numerical ...
We show how high-resolution NMR spectra can be obtained for solids for which the spectra are normally broadened due to structural disorder. The method relies on correlations in the chemical shifts between pairs of coupled spins. It is found experimentally ...
Microfabricated small-volume NMR probes consisting of electroplated planar microcoils integrated on a glass substrate with etched microfluidic channels are fabricated and tested. 1H NMR spectra are acquired at 300MHz with three different probes having obse ...
The translational diffusion coeff. of an integral membrane protein/surfactant complex has been measured using a novel pulsed field gradient NMR method. In this new approach, the information about the localization of the mols. is temporarily stored in the f ...
Taking advantage of the Curie contribution to the relaxation of the protons in the Tb(III) complex, and the quadrupolar relaxation of the 17O and 2H nuclei on the Eu(III) complex, the effect of the internal motion of the water molecule bound to [Ln(DOTAM)( ...
Two sets of cross-correlated relaxation rates involving chem. shift anisotropy and dipolar interactions have been measured in an RNA kissing complex. In one case, both the CSA and dipolar interaction tensors are located on the same nucleotide base and are ...