Publications related to Ligand cone angle

New Strategies for the Functionalization of Alkenes Exploiting Tethering Chemistry and Ring Strain

Amino alcohols, cyclopropanes and nitriles are privileged structural motifs found in the scaffold of natural products and bioactive compounds. In addition, they are versatile building blocks in organic chemistry. The development of new and increasingly eff ...

EPFL2021

Ligand Effects in Low-Valent Co(I) Clathrochelate Complexes

Rosario Scopelliti, Kay Severin, Farzaneh Fadaei Tirani, Ophélie Marie Planes

Clathrochelate complexes of cobalt are known in the oxidation states I, II, and III. Low-valent Co(I) complexes are highly reactive compounds, and there is only limited knowledge about their structures in the solid state. Herein, we describe the crystallog ...

WILEY-V C H VERLAG GMBH2021

Ligand Binding to the Collagen VI Receptor Triggers a Talin-to-RhoA Switch that Regulates Receptor Endocytosis

Françoise Gisou van der Goot Grunberg, Matteo Dal Peraro, Laurence Gouzi Abrami, Luciano Andres Abriata, Béatrice Kunz

Capillary morphogenesis gene 2 (CMG2/ANTXR2) is a cell surface receptor for both collagen VI and anthrax toxin. Biallelic loss-of-function mutations in CMG2 lead to a severe condition, hyaline fibromatosis syndrome (HFS). We have here dissected a network o ...

CELL PRESS2020

Bimodal atomic force microscopy for the characterization of thiolated self-assembled monolayers

Francesco Stellacci, Quy Ong Khac, Nikolaos Nianias, Evangelia-Nefeli Athanasopoulou

Surface coatings are becoming an integral part of materials. In recent years, molecular coatings have found larger acceptance and uses. Among them, self-assembled monolayers (SAMs) are attractive due to their inherent versatility, manufacturability, and sc ...

ROYAL SOC CHEMISTRY2018

Water as a Hydride Source in Palladium-Catalyzed Enantioselective Reductive Heck Reactions

Qian Wang, Jieping Zhu, Wangqing Kong

Pd-catalyzed intramolecular asymmetric carbopalladation of N-aryl acrylamides followed by reduction of C(sp3)-Pd intermediate using diboron–water as a hydride source afforded enantioenriched 3,3-disubstituted oxindoles in high yields and enantioselectiviti ...

Wiley-Blackwell2017

Accessing and predicting the kinetic profiles of homogeneous catalysts from volcano plots

Matthew Wodrich, Michael Markus Busch

Volcano plots are frequently used as aids in the search for new heterogeneous and electrochemical catalysts. These tools successfully predict catalytic processes based solely on thermodynamic descriptions, which also capably describe many aspects of the ca ...

Royal Soc Chemistry2016

Nonsteroidal Anti-inflammatory-Organometallic Anticancer Compounds

Paul Joseph Dyson, Rosario Scopelliti, Mylène Soudani, Emilia Paunescu, Sarah Mcarthur

Compounds that combine metal-based drugs with covalently linked targeted organic agents have been shown, in some instances, to exhibit superior anticancer properties compared to the individual counterparts. Within this framework, we prepared a series of or ...

Amer Chemical Soc2016

Modulating the Anticancer Activity of Ruthenium(II)-Arene Complexes

Paul Joseph Dyson, Rosario Scopelliti, Patrycja Nowak-Sliwinska, Catherine Marie Amélie Clavel, Emilia Paunescu

Following the identification of [Ru(eta(6)-p-cymene)Cl-2(1H,1H,2H,2H-perfluorodecyl-3-(pyridin-3-yl)propanoate)], a ruthenium(II)arene complex with a perfluoroalkyl-modified ligand that displays remarkable in vitro cancer cell selectivity, a series of stru ...

Amer Chemical Soc2015

Chat with Graph Search

Ask any question about EPFL courses, lectures, exercises, research, news, etc. or try the example questions below.

DISCLAIMER: The Graph Chatbot is not programmed to provide explicit or categorical answers to your questions. Rather, it transforms your questions into API requests that are distributed across the various IT services officially administered by EPFL. Its purpose is solely to collect and recommend relevant references to content that you can explore to help you answer your questions.

Ligand cone angle

New Strategies for the Functionalization of Alkenes Exploiting Tethering Chemistry and Ring Strain

Ligand Effects in Low-Valent Co(I) Clathrochelate Complexes

The Role of Percent Volume Buried in the Characterization of Copper(I) Complexes for Lighting Purposes

Ligand Binding to the Collagen VI Receptor Triggers a Talin-to-RhoA Switch that Regulates Receptor Endocytosis

Development of a novel carboxamide-based off-on switch fluorescence sensor: Hg2+, Zn(2+)and Cd2+

Bimodal atomic force microscopy for the characterization of thiolated self-assembled monolayers

Water as a Hydride Source in Palladium-Catalyzed Enantioselective Reductive Heck Reactions

Accessing and predicting the kinetic profiles of homogeneous catalysts from volcano plots

Nonsteroidal Anti-inflammatory-Organometallic Anticancer Compounds

Modulating the Anticancer Activity of Ruthenium(II)-Arene Complexes

Graph Chatbot

Chat with Graph Search

New Strategies for the Functionalization of Alkenes Exploiting Tethering Chemistry and Ring Strain

Ligand Effects in Low-Valent Co(I) Clathrochelate Complexes

The Role of Percent Volume Buried in the Characterization of Copper(I) Complexes for Lighting Purposes

Water as a Hydride Source in Palladium-Catalyzed Enantioselective Reductive Heck Reactions

Accessing and predicting the kinetic profiles of homogeneous catalysts from volcano plots

Nonsteroidal Anti-inflammatory-Organometallic Anticancer Compounds

Modulating the Anticancer Activity of Ruthenium(II)-Arene Complexes

Bimodal atomic force microscopy for the characterization of thiolated self-assembled monolayers

Development of a novel carboxamide-based off-on switch fluorescence sensor: Hg2+, Zn(2+)and Cd2+

Ligand Binding to the Collagen VI Receptor Triggers a Talin-to-RhoA Switch that Regulates Receptor Endocytosis