Athermalization, in the field of optics, is the process of achieving optothermal stability in optomechanical systems. This is done by minimizing variations in optical performance over a range of temperatures. Optomechanical systems are typically made of several materials with different thermal properties. These materials compose the optics (refractive or reflective elements) and the mechanics (optical mounts and system housing). As the temperature of these materials change, the volume and index of refraction will change as well, increasing strain and aberration content (primarily defocus). Compensating for optical variations over a temperature range is known as athermalizing a system in optical engineering. Thermal expansion is the driving phenomena for the extensive and intensive property changes in an optomechanical system. Extensive property changes, such as volume, alter the shape of optical and mechanical components. Systems are geometrically optimized for optical performance and are sensitive to components changing shape and orientation. While volume is a three dimensional parameter, thermal changes can be modeled in a single dimension with linear expansion, assuming an adequately small temperature range. For examples, glass manufacturer Schott provides the coefficient of linear thermal expansion for a temperature range of -30 C to 70 C. The change in length of a material is a function of the change in temperature with respect to the standard measurement temperature, . This temperature is typically room temperature or 22 degrees Celsius. Where is the length of a material at temperature , is the length of the material at temperature , is the change in temperature, and is the coefficient of thermal expansion. These equations describe how diameter, thickness, radius of curvature, and element spacing change as a function of temperature. The dominant intensive property change, in terms of optical performance, is the index of refraction. The refractive index of glass is a function of wavelength and temperature.

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