Emissivity | EPFL Graph Search

The emissivity of the surface of a material is its effectiveness in emitting energy as thermal radiation. Thermal radiation is electromagnetic radiation that most commonly includes both visible radiation (light) and infrared radiation, which is not visible to human eyes. A portion of the thermal radiation from very hot objects (see photograph) is easily visible to the eye. The emissivity of a surface depends on its chemical composition and geometrical structure. Quantitatively, it is the ratio of the thermal radiation from a surface to the radiation from an ideal black surface at the same temperature as given by the Stefan–Boltzmann law. (A comparison with Planck's law is used if one is concerned with particular wavelengths of thermal radiation.) The ratio varies from 0 to 1. The surface of a perfect black body (with an emissivity of 1) emits thermal radiation at the rate of approximately 448 watts per square metre (W/m2) at a room temperature of . Objects general

Dynamics of Electronic and Ionic Charges in Cyanine Organic Semiconductor Devices

Sandra Christina Jenatsch

Organic semiconductor materials have been widely applied in optoelectronic devices to replace their inorganic counterparts and explore new fields of applications. Due to their high extinction coefficients, chemical tunability and solubility, cyanine dyes are an interesting class of molecules to be employed in organic semiconductor devices. Their beneficial properties have been demonstrated in organic solar cells (OSC), photodetectors and recently in organic light-emitting electrochemical cells (OLEC). The focus of this thesis is to analyse different aspects regarding the dynamics of electronic and ionic charges in cyanine based devices. Models and conclusions are not restricted to cyanine based devices but can potentially be applied in various systems where combined ionic and electronic charges are present. In order to focus on electronic processes in OSCs, a combination of steady-state, transient and impedance analysis is used. It is resolved that trapped charges can be introduced at the dye/hole extracting layer interface by using specific solvents for the cyanine layer fabrication. These measurements also reveal the low hole mobility of cyanine films which in turn limits the possible upper layer thickness in OSCs. A frequently used way to enhance the conductivity of organic semiconductors is the addition of extra charges by chemical doping. This concept is employed for a near-infrared absorbing dye which is used as donor in a bilayer solar cell. The dependence of all figures of merit versus doping concentration and layer thickness is studied in detail. It is found that the performance of the optimised cell is not further improved by doping, but that it presents a good option if thicker layers are required, e.g. on rough substrates. Furthermore, the stability and degradation pathway of the p-doped species is analysed. This information is of general relevance as they also occur after charge transfer at the heterojunction interface of an OSC and during operation of OLECs. The dynamics of ionic charge carriers is separated into two contributions. In a first step, the steady-state diffusion profile of the counter ion within a cyanine/fullerene bilayer structure is scrutinised using different profiling techniques. An unexpected constant ion profile is found throughout the C60 layer. Simultaneously, the potential within the acceptor is measured by the Kelvin probe technique. A mechanism of combined electron and ion transfer from the C60 to the dye and vice versa is proposed which is in agreement with the experimental results. A prerequisite for OLEC operation is the mobility of ionic charge carriers. Their dynamics in cyanine salts under the effect of an external field is therefore studied in such devices. Several methods are developed and applied to characterise the dynamic p-i-n structure in detail, i.e. the position and width of the intrinsic region as well as the doping concentrations in p- and n-doped regions. The combination of all these methods helps to understand the transient behaviour of these cyanine devices but can also be adapted to other OLEC systems. A major drawback of cyanine dyes as emissive material is their low fluorescence quantum yield in solid films. To overcome this restriction and improve the OLEC efficiency, host-guest systems with various visibly emitting dyes are studied. The gain in fluorescence quantum yield in the film can directly be transferred to an increase in external quantum efficiency of the device.

EPFL2017

Energy-Efficient Sol-Gel Process for Production of Nanocomposite Absorber Coatings for Tubular Solar Thermal Collectors

Yannik Antonetti, Marina Garcia Gonzalez, Thomas Gascou, Martin Joly, Martin Python, Andreas Schueler

The energy efficiency of production processes for components of solar energy systems is an important issue. Other factors which are important for the production of products such as black selective solar coatings include production speed, cycle time and homogeneity of the coating, as well as the minimization of the quantity of the needed chemical precursors. In this paper a new energy efficient production process is presented for production of optically selective coatings for solar thermal absorbers. The latter should ideally behave as a black body, absorbing a maximum of the incoming solar radiation, while minimizing energy losses by infrared radiation, acting as an infrared mirror. The used method to produce such coatings is sol-gel dip-coating. The optical and morphological properties of the Cu-Co-Mn-Si-O based triple layer have been characterized by spectrophotometry, electron microscopy and time of flight secondary electron microscopy. After optimization of the multilayer design, a solar absorptance of 0.95 and a thermal emissivity of 0.12 at 100°C have been achieved. The intermediate Cu-Co-Mn-Si-O layer was analyzed by high resolution transmission electron microscopy. The likewise obtained images show an agglomeration of crystalline grains with 10-20nm in diameter. Therefore, we can consider that the Cu-Co-Mn-Si-O phase is nanocrystalline. In order to roughly estimate the corrosion resistance of the coating in an acidic environment, a simple corrosion test in harsh conditions was designed. With respect to a commercially available durable black chrome coating, this test of corrosion resistance confirmed the durability of the novel sol-gel coating in an acidic environment. Moreover, the excellent stability at elevated temperatures in ambient air makes the coating an interesting candidate for solar applications involving concentrated solar radiation, such as the generation of solar electricity (concentrated solar power), industrial process heating and solar cooling. For that reason, prototype coatings consisting of stacks of three individual layers were deposited on 2 meter long stainless steel tubes.

EPFL Solar Energy and Building Physics Laboratory (LESO-PB)2013

Novel black selective coating for tubular solar absorbers based on a sol-gel method

Yannik Antonetti, Marina Garcia Gonzalez, Thomas Gascou, Martin Joly, Martin Python, Jean-Louis Scartezzini, Andreas Schueler

Multi layered chrome-free black selective surfaces for solar thermal energy conversion were produced by a low-cost sol gel dip-coating method. The optical properties of the Cu-Co-Mn-Si-O based nanocrystalline thin films have been characterized by spectrophotometry and spectroscopic ellipsometry. After optimization of the multilayer design, a solar absorptance of 0.95 and a thermal emissivity of 0.12 at 100 degrees C have been achieved. The stability of the coatings at 360 degrees C in air surpasses the one of the conventional robust black chrome coatings existing on the market. Additionally, the corrosion resistance has been tested in acidic environment. The novel black selective coatings were deposited with satisfactory homogeneity on 2 m long stainless steel tubes. Fast and energy-efficient induction heating was used for thermal annealing. Receiver tubes coated in this manner are especially interesting candidate for applications working with concentrated solar power (CSP) such as power plants for solar thermal electricity generation, co- and tri-generation. (C) 2013 Elsevier Ltd. All rights reserved..

Elsevier2013