Determination of the day of the weekThe determination of the day of the week for any date may be performed with a variety of algorithms. In addition, perpetual calendars require no calculation by the user, and are essentially lookup tables. A typical application is to calculate the day of the week on which someone was born or a specific event occurred. In numerical calculation, the days of the week are represented as weekday numbers. If Monday is the first day of the week, the days may be coded 1 to 7, for Monday through Sunday, as is practiced in ISO 8601.
WeekA week is a unit of time equal to seven days. It is the standard time period used for short cycles of days in most parts of the world. The days are often used to indicate common work days and rest days, as well as days of worship. Weeks are often mapped against yearly calendars, but are typically not the basis for them, as weeks are not based on astronomy. The modern seven-day week can be traced back to the Babylonians, who used it within their calendar.
Ligand field theoryLigand field theory (LFT) describes the bonding, orbital arrangement, and other characteristics of coordination complexes. It represents an application of molecular orbital theory to transition metal complexes. A transition metal ion has nine valence atomic orbitals - consisting of five nd, one (n+1)s, and three (n+1)p orbitals. These orbitals are of appropriate energy to form bonding interaction with ligands. The LFT analysis is highly dependent on the geometry of the complex, but most explanations begin by describing octahedral complexes, where six ligands coordinate to the metal.
Coordination complexA coordination complex is a chemical compound consisting of a central atom or ion, which is usually metallic and is called the coordination centre, and a surrounding array of bound molecules or ions, that are in turn known as ligands or complexing agents. Many metal-containing compounds, especially those that include transition metals (elements like titanium that belong to the periodic table's d-block), are coordination complexes. Coordination complexes are so pervasive that their structures and reactions are described in many ways, sometimes confusingly.
Doomsday ruleThe Doomsday rule, Doomsday algorithm or Doomsday method is an algorithm of determination of the day of the week for a given date. It provides a perpetual calendar because the Gregorian calendar moves in cycles of 400 years. The algorithm for mental calculation was devised by John Conway in 1973, drawing inspiration from Lewis Carroll's perpetual calendar algorithm. It takes advantage of each year having a certain day of the week upon which certain easy-to-remember dates, called the doomsdays, fall; for example, the last day of February, 4/4, 6/6, 8/8, 10/10, and 12/12 all occur on the same day of the week in any year.
