Strategies to Break Linear Scaling Relationships in Catalysis

This lecture delves into the strategies employed to break linear scaling relationships in catalysis, focusing on the concept of volcanoes as a systematic way for optimization. The instructor discusses the origins of volcanoes in catalysis, the challenges they present, and the need to go beyond traditional approaches by introducing complexities in catalytic systems. Various methods are explored, such as controlling ensembles, using ligands, and doping, to break the symmetry and enhance catalytic performance. The lecture also covers the use of single atoms, magnetic enhancement, and external forces to modify electronic structures and improve catalytic activity, providing insights into the future of catalysis research.