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This lecture explores the use of liquid-vapor phase change for sustainable high-performance cooling, addressing the increasing demand for cooling and the challenges of carbon emissions. It delves into the fundamental physics of evaporation, the broad applications of liquid-vapor phase change, and the development of novel materials for passive cooling. The instructor presents innovative solutions such as hierarchical membrane evaporators, hydrogel-aerogel bilayers, and insulated cooling systems that leverage evaporation and radiation. The lecture also discusses the integration of these technologies into air conditioning systems and their potential impact on sustainability, showcasing ongoing efforts in robust hybrid cooling panels.