HH, or h, is the eighth letter in the Latin alphabet, used in the modern English alphabet, including the alphabets of other western European languages and others worldwide. Its name in English is aitch (pronounced eɪtʃ, plural aitches), or regionally haitch heɪtʃ. The original Semitic letter Heth most likely represented the voiceless pharyngeal fricative (ħ). The form of the letter probably stood for a fence or posts. The Greek Eta 'Η' in archaic Greek alphabets, before coming to represent a long vowel, /ɛː/, still represented a similar sound, the voiceless glottal fricative /h/.
H-droppingH-dropping or aitch-dropping is the deletion of the voiceless glottal fricative or "H-sound", [h]. The phenomenon is common in many dialects of English, and is also found in certain other languages, either as a purely historical development or as a contemporary difference between dialects. Although common in most regions of England and in some other English-speaking countries, and linguistically speaking a neutral evolution in languages, H-dropping is often stigmatized as a sign of careless or uneducated speech.
H with strokeĦ (minuscule: ħ) is a letter of the Latin alphabet, derived from H with the addition of a bar. It is used in Maltese for a voiceless pharyngeal fricative consonant (corresponding to the letter heth of Semitic abjads: ح, ח). Lowercase ħ is used in the International Phonetic Alphabet for the same sound. In Unicode, the special character ħ (U+210F), represents the reduced Planck constant of quantum mechanics. In this context, it is pronounced "h-bar". The lowercase resembles the Cyrillic letter Tshe (ћ), or the astronomical symbol of Saturn (♄).
Reaction mechanismIn chemistry, a reaction mechanism is the step by step sequence of elementary reactions by which overall chemical reaction occurs. A chemical mechanism is a theoretical conjecture that tries to describe in detail what takes place at each stage of an overall chemical reaction. The detailed steps of a reaction are not observable in most cases. The conjectured mechanism is chosen because it is thermodynamically feasible and has experimental support in isolated intermediates (see next section) or other quantitative and qualitative characteristics of the reaction.
Rate-determining stepIn chemical kinetics, the overall rate of a reaction is often approximately determined by the slowest step, known as the rate-determining step (RDS or RD-step or r/d step) or rate-limiting step. For a given reaction mechanism, the prediction of the corresponding rate equation (for comparison with the experimental rate law) is often simplified by using this approximation of the rate-determining step. In principle, the time evolution of the reactant and product concentrations can be determined from the set of simultaneous rate equations for the individual steps of the mechanism, one for each step.
