Symmetry Operations in Molecules

This lecture covers the concept of symmetry operations in molecules, focusing on chiral molecules without an inversion center. The instructor explains how molecules lacking certain symmetry elements are chiral, and how symmetry elements can be classified as proper or improper rotations. The lecture delves into the relationship between mirror images and chiral molecules, demonstrating how certain symmetry operations interlink the original and mirror images. Additionally, the lecture explores the process of identifying point groups in molecules, emphasizing the importance of recognizing rotational and mirror symmetry elements. Through detailed examples and exercises, students learn how to determine the point group of a molecule based on its symmetry properties.

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CH-250: Mathematical methods in chemistry

This course consists of two parts. The first part covers basic concepts of molecular symmetry and the application of group theory to describe it. The second part introduces Laplace transforms and Four

Symmetry () in everyday language refers to a sense of harmonious and beautiful proportion and balance. In mathematics, the term has a more precise definition and is usually used to refer to an object that is invariant under some transformations, such as translation, reflection, rotation, or scaling. Although these two meanings of the word can sometimes be told apart, they are intricately related, and hence are discussed together in this article.

In chemistry, molecular symmetry describes the symmetry present in molecules and the classification of these molecules according to their symmetry. Molecular symmetry is a fundamental concept in chemistry, as it can be used to predict or explain many of a molecule's chemical properties, such as whether or not it has a dipole moment, as well as its allowed spectroscopic transitions. To do this it is necessary to use group theory. This involves classifying the states of the molecule using the irreducible representations from the character table of the symmetry group of the molecule.

In group theory, the symmetry group of a geometric object is the group of all transformations under which the object is invariant, endowed with the group operation of composition. Such a transformation is an invertible mapping of the ambient space which takes the object to itself, and which preserves all the relevant structure of the object. A frequent notation for the symmetry group of an object X is G = Sym(X). For an object in a metric space, its symmetries form a subgroup of the isometry group of the ambient space.

In geometry, an object has symmetry if there is an operation or transformation (such as translation, scaling, rotation or reflection) that maps the figure/object onto itself (i.e., the object has an invariance under the transform). Thus, a symmetry can be thought of as an immunity to change. For instance, a circle rotated about its center will have the same shape and size as the original circle, as all points before and after the transform would be indistinguishable.

In group theory, geometry, representation theory and molecular geometry, a symmetry operation is a geometric transformation of an object that leaves the object looking the same after it has been carried out. For example, as transformations of an object in space, rotations, reflections and inversions are all symmetry operations. Such symmetry operations are performed with respect to symmetry elements (for example, a point, line or plane).