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This lecture covers the fundamentals of thermodynamics, phase diagrams, and their applications in materials science. It delves into the behavior of matter under external fields, equilibrium states, and phase transitions. The instructor explains the significance of Gibbs free energy, entropy, enthalpy, and the laws of thermodynamics. Additionally, the lecture explores unary and binary phase diagrams, mixing enthalpy, and the role of phase diagrams in alloy design and processing.