Sigma bondIn chemistry, sigma bonds (σ bonds) are the strongest type of covalent chemical bond. They are formed by head-on overlapping between atomic orbitals. Sigma bonding is most simply defined for diatomic molecules using the language and tools of symmetry groups. In this formal approach, a σ-bond is symmetrical with respect to rotation about the bond axis. By this definition, common forms of sigma bonds are s+s, pz+pz, s+pz and dz2+dz2 (where z is defined as the axis of the bond or the internuclear axis).
Gas diffusion electrodeGas diffusion electrodes (GDE) are electrodes with a conjunction of a solid, liquid and gaseous interface, and an electrical conducting catalyst supporting an electrochemical reaction between the liquid and the gaseous phase. GDEs are used in fuel cells, where oxygen and hydrogen react at the gas diffusion electrodes, to form water, while converting the chemical bond energy into electrical energy. Usually the catalyst is fixed in a porous foil, so that the liquid and the gas can interact.
Net (polyhedron)In geometry, a net of a polyhedron is an arrangement of non-overlapping edge-joined polygons in the plane which can be folded (along edges) to become the faces of the polyhedron. Polyhedral nets are a useful aid to the study of polyhedra and solid geometry in general, as they allow for physical models of polyhedra to be constructed from material such as thin cardboard.
Dynkin diagramIn the mathematical field of Lie theory, a Dynkin diagram, named for Eugene Dynkin, is a type of graph with some edges doubled or tripled (drawn as a double or triple line). Dynkin diagrams arise in the classification of semisimple Lie algebras over algebraically closed fields, in the classification of Weyl groups and other finite reflection groups, and in other contexts. Various properties of the Dynkin diagram (such as whether it contains multiple edges, or its symmetries) correspond to important features of the associated Lie algebra.
Non-covalent interactionIn chemistry, a non-covalent interaction differs from a covalent bond in that it does not involve the sharing of electrons, but rather involves more dispersed variations of electromagnetic interactions between molecules or within a molecule. The chemical energy released in the formation of non-covalent interactions is typically on the order of 1–5 kcal/mol (1000–5000 calories per 6.02 molecules). Non-covalent interactions can be classified into different categories, such as electrostatic, π-effects, van der Waals forces, and hydrophobic effects.