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A rigorous mathematical model is developed for the complex impedance of a solid-state electrochemical cell, which is commonly used for the measurement of oxygen transport, oxygen exchange kinetics and thermodynamic properties of nonstoichiometric mixed con ...
Abstract: A short overview of recent work on electroceramic materials relevant to methane-fueled SOFC systems is given. Various fuel feed options are considered, such as pure methane, biogas, and the addition of reforming agents. The principle and implemen ...
Chemical diffusion (D) and surface exchange (k) coefficients for SrFeO3-delta were measured using an electrochemical cell combined with electrochemical impedance spectroscopy (EIS) and potential step technique (PS) in the temperature range of 850-915°C. A ...
Oxygen diffusion is treated in a dense electronically conducting cobaltate pellet blocked ionically on one surface, electronically on the other, and sealed on its cylindrical periphery. A procedure is developed for extracting the chemical diffusion and sur ...
