Person
Zdenek Samec
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Related publications (14)
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Ionic partition diagram of tetraphenylporphyrin at the water|1,2-dichloroethane interface
Hubert Girault, Manuel Alejandro Méndez Agudelo, Bin Su, Raheleh Partovi Nia, Zdenek Samec
diagram of 5,10,15,20-tetraphenyl-21H,23H-porphine (H2TPP) at the water|1,2-dichloroethane interface using a simple Born solvation model. This zone diagram shows under which form this porphyrin is present, i.e. neutral, monoprotonated or diprotonated, and ...
Elsevier2011Fine tuning of the catalytic effect of a metal-free porphyrin on the homogeneous oxygen reduction
The catalytic effect of tetraphenylporphyrin on the oxygen reduction with ferrocene in 1,2-dichloroethane can be finely tuned by varying the molar ratio of the acid to the catalyst present in the solution. The mechanism involves binding of molecular oxygen ...
Royal Society of Chemistry2011Oxygen and proton reduction by decamethylferrocene in non-aqueous acidic media
Hubert Girault, Manuel Alejandro Méndez Agudelo, Bin Su, Peiyu Ge, Imren Hatay, Zdenek Samec
Experimental studies and density functional theory (DFT) computations suggest that oxygen and proton reduction by decamethylferrocene (DMFc) in 1,2-dichloroethane involves protonated DMFc, DMFcH+, as an active intermediate species, producing hydrogen perox ...
Royal Society of Chemistry2010